{"title":"发光二极管驱动的 MOF 催化有氧 C-H 和 C-C 键氧化作用","authors":"Mehdi Sheykhan, Mona Bahmani, Masoumeh Abbasnia","doi":"10.1039/d4cy00892h","DOIUrl":null,"url":null,"abstract":"A novel LED-driven aerobic C–H oxidation is reported <em>via</em> MOF catalysis, eliminating the need for metal sources, additives, or oxidants. This approach also works well with aerobic oxygenation of C–H bonds and C–C cleavage/oxygenation of both alkenes and alkynes all at room temperature. Polyaromatic hydrocarbons were also successfully oxidized under these conditions indicating a broad, extendable scope.","PeriodicalId":66,"journal":{"name":"Catalysis Science & Technology","volume":null,"pages":null},"PeriodicalIF":4.4000,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Efficient LED-driven MOF-catalysis for aerobic C–H and C–C bond oxidation\",\"authors\":\"Mehdi Sheykhan, Mona Bahmani, Masoumeh Abbasnia\",\"doi\":\"10.1039/d4cy00892h\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A novel LED-driven aerobic C–H oxidation is reported <em>via</em> MOF catalysis, eliminating the need for metal sources, additives, or oxidants. This approach also works well with aerobic oxygenation of C–H bonds and C–C cleavage/oxygenation of both alkenes and alkynes all at room temperature. Polyaromatic hydrocarbons were also successfully oxidized under these conditions indicating a broad, extendable scope.\",\"PeriodicalId\":66,\"journal\":{\"name\":\"Catalysis Science & Technology\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":4.4000,\"publicationDate\":\"2024-09-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Catalysis Science & Technology\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1039/d4cy00892h\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis Science & Technology","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4cy00892h","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Efficient LED-driven MOF-catalysis for aerobic C–H and C–C bond oxidation
A novel LED-driven aerobic C–H oxidation is reported via MOF catalysis, eliminating the need for metal sources, additives, or oxidants. This approach also works well with aerobic oxygenation of C–H bonds and C–C cleavage/oxygenation of both alkenes and alkynes all at room temperature. Polyaromatic hydrocarbons were also successfully oxidized under these conditions indicating a broad, extendable scope.
期刊介绍:
A multidisciplinary journal focusing on cutting edge research across all fundamental science and technological aspects of catalysis.
Editor-in-chief: Bert Weckhuysen
Impact factor: 5.0
Time to first decision (peer reviewed only): 31 days