固态氩中氰乙炔的光化学再研究

Pub Date : 2024-09-04 DOI:10.1063/10.0028163

Thomas G. Custer, Claudine Crépin, Marcin Gronowski, Arun-Libertsen Lawzer, Robert Kołos

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引用次数: 0

摘要

利用同位素（2H 和 15N）标记和红外吸收光谱研究了紫外线诱导的氰乙炔在低温惰性气体基质中的转化。研究结果表明，所有观察到的异构化过程都涉及单个独立的前体分子。没有发现意味着来自不同分子的碎片重组的光产物。

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Photochemistry of cyanoacetylene in solid argon revisited

Isotopic (2H and 15N) labelling and IR absorption spectroscopy have been used to study UV-induced transformations of cyanoacetylene in cryogenic noble gas matrices. The results obtained indicate that all observed isomerization processes involve single, isolated molecules of the precursor. No photoproducts have been found that would imply the recombination of fragments originating from different molecules.

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