戊酸倍他米松激素的热力学函数

IF 0.7 4区化学 Q4 CHEMISTRY, PHYSICAL

Russian Journal of Physical Chemistry A Pub Date : 2024-09-09 DOI:10.1134/S0036024424700985

A. V. Knyazev, N. N. Smirnova, O. V. Stepanova, S. S. Knyazeva, A. S. Shipilova, S. V. Chuprova

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引用次数: 0

摘要

摘要通过精确的真空绝热量热法，首次测定了戊酸倍他米松在 5.5 至 346 K 范围内的热容量随温度的变化。根据实验数据确定了戊酸倍他米松在 T → 0 至 350 K 温度范围内的热力学函数，即热容量、焓 H°(T) - H°(0)、熵 S°(T) - S°(0)和吉布斯函数 G°(T) - H°(0)。热膨胀系数是通过低温粉末 X 射线衍射仪测定的。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Thermodynamic Functions of the Betamethasone Valerate Hormone

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Thermodynamic Functions of the Betamethasone Valerate Hormone

The temperature dependence of the heat capacity of betamethasone valerate in the range from 5.5 to 346 K was measured for the first time by precise vacuum adiabatic calorimetry. The thermodynamic functions of betamethasone valerate, namely, heat capacity, enthalpy H°(T) – H°(0), entropy S°(T) – S°(0), and Gibbs function G°(T) – H°(0) were determined for the temperature range from T → 0 to 350 K based on the experimental data. The thermal expansion coefficients were determined by low temperature powder X-ray diffractometry.

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来源期刊

Russian Journal of Physical Chemistry A 化学-物理化学

CiteScore

1.20

自引率

14.30%

发文量

376

审稿时长

5.1 months

期刊介绍： Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world. Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.