P. D. Krutov, V. E. Maizlish, O. N. Krutova, V. V. Chernikov, M. I. Bazanov, E. E. Kiptikova
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引用次数: 0
摘要
摘要 获得了四-3-羧基酞菁与铜的不溶于水的络合物。在 298.15 K 的不同 KOH 浓度（从 0.002 到 0.02 mol/L）的水溶液中溶解结晶四-3-羧基金属酞菁所产生的热效应是通过直接量热法测定的。测量是在热量计中进行的，热量计使用等温壳，自动记录温度，并在 T = (293.15-308.15) ± 0.01 K 和 P = 100.5 ± 0.7 kPa 时进行电气校准。计算了四-3-羧基酞菁络合物与铜在水溶液中解离产物的标准形成焓。使用 HEAT 计算机程序计算了逐步解离的热效应。
Thermochemistry of the Dissolution of Copper Tetra-3-carboxyphtalocyanine in Aqueous Solutions of KOH at 298.15 K
Abstract
A complex of tetra-3-carboxyphthalocyanine with copper that is insoluble in water is obtained. Thermal effects from dissolving crystalline tetra-3-carboxymetalphthalocyanine in aqueous solutions of various KOH concentrations (from 0.002 to 0.02 mol/L) at 298.15 K are determined via direct calorimetry. Measurements are made in a calorimeter using an isothermal shell with automatic recording of the temperature and electrical calibration at T = (293.15–308.15) ± 0.01 K and P = 100.5 ± 0.7 kPa. Standard enthalpies of formation of the products of dissociation of the tetra-3-carboxyphthalocyanine complex with copper in aqueous solution are calculated. Thermal effects of stepwise dissociation are calculated using the HEAT computer program.
期刊介绍：
Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world.
Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.
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