{"title":"ZnMoO4-TiO2 的介电性能和导电性能:探索高温性能和应用潜力","authors":"Subhangi Kalingani, Satyaprakash Narayan Das, Satyanaryan Bhuyan","doi":"10.1007/s13538-024-01609-5","DOIUrl":null,"url":null,"abstract":"<div><p>Considering ceramic engineering advances, this study explores ZnMoO<sub>4</sub>-TiO<sub>2</sub> electronic composite synthesis. This is synthesized using a solid-state mixed oxide reaction technique. Sample is calcined at 780 °C and sintered at 810 °C. The X-ray diffraction pattern of the sample structure matches with the JCPDS reference codes 98–000-4862 and 98–002-2025. Ambient temperature SEM and EDAX reveal the material’s structure and composition. Compound microstructure exhibits continuous grain dispersion and unique porosity. Dielectric, loss tangent, and conductivity were comprehensively analyzed from 30 to 450 °C and 1 kilohertz (kHz) to 1 megahertz (MHz). At temperatures above 300 °C, the dielectric constant increases. The activation energy for electrical conductivity exhibits a range of values, specifically from 0.82 to 1.92 eV at various frequencies, when the temperature increases from 400 to 450 °C. UV–visible spectroscopy determined the band gap energy of 3.12 eV, with absorption peaks at 205 and 390 nm. Based on these findings, ZnMoO<sub>4</sub>-TiO<sub>2</sub> may be suitable for humidity sensors and other electrical and electronic devices.</p></div>","PeriodicalId":499,"journal":{"name":"Brazilian Journal of Physics","volume":"54 6","pages":""},"PeriodicalIF":1.5000,"publicationDate":"2024-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Dielectric and Conductive Properties of ZnMoO4-TiO2: Exploring High-Temperature Performance and Application Potential\",\"authors\":\"Subhangi Kalingani, Satyaprakash Narayan Das, Satyanaryan Bhuyan\",\"doi\":\"10.1007/s13538-024-01609-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Considering ceramic engineering advances, this study explores ZnMoO<sub>4</sub>-TiO<sub>2</sub> electronic composite synthesis. This is synthesized using a solid-state mixed oxide reaction technique. Sample is calcined at 780 °C and sintered at 810 °C. The X-ray diffraction pattern of the sample structure matches with the JCPDS reference codes 98–000-4862 and 98–002-2025. Ambient temperature SEM and EDAX reveal the material’s structure and composition. Compound microstructure exhibits continuous grain dispersion and unique porosity. Dielectric, loss tangent, and conductivity were comprehensively analyzed from 30 to 450 °C and 1 kilohertz (kHz) to 1 megahertz (MHz). At temperatures above 300 °C, the dielectric constant increases. The activation energy for electrical conductivity exhibits a range of values, specifically from 0.82 to 1.92 eV at various frequencies, when the temperature increases from 400 to 450 °C. UV–visible spectroscopy determined the band gap energy of 3.12 eV, with absorption peaks at 205 and 390 nm. Based on these findings, ZnMoO<sub>4</sub>-TiO<sub>2</sub> may be suitable for humidity sensors and other electrical and electronic devices.</p></div>\",\"PeriodicalId\":499,\"journal\":{\"name\":\"Brazilian Journal of Physics\",\"volume\":\"54 6\",\"pages\":\"\"},\"PeriodicalIF\":1.5000,\"publicationDate\":\"2024-09-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Brazilian Journal of Physics\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s13538-024-01609-5\",\"RegionNum\":4,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"PHYSICS, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Brazilian Journal of Physics","FirstCategoryId":"101","ListUrlMain":"https://link.springer.com/article/10.1007/s13538-024-01609-5","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"PHYSICS, MULTIDISCIPLINARY","Score":null,"Total":0}
Dielectric and Conductive Properties of ZnMoO4-TiO2: Exploring High-Temperature Performance and Application Potential
Considering ceramic engineering advances, this study explores ZnMoO4-TiO2 electronic composite synthesis. This is synthesized using a solid-state mixed oxide reaction technique. Sample is calcined at 780 °C and sintered at 810 °C. The X-ray diffraction pattern of the sample structure matches with the JCPDS reference codes 98–000-4862 and 98–002-2025. Ambient temperature SEM and EDAX reveal the material’s structure and composition. Compound microstructure exhibits continuous grain dispersion and unique porosity. Dielectric, loss tangent, and conductivity were comprehensively analyzed from 30 to 450 °C and 1 kilohertz (kHz) to 1 megahertz (MHz). At temperatures above 300 °C, the dielectric constant increases. The activation energy for electrical conductivity exhibits a range of values, specifically from 0.82 to 1.92 eV at various frequencies, when the temperature increases from 400 to 450 °C. UV–visible spectroscopy determined the band gap energy of 3.12 eV, with absorption peaks at 205 and 390 nm. Based on these findings, ZnMoO4-TiO2 may be suitable for humidity sensors and other electrical and electronic devices.
期刊介绍:
The Brazilian Journal of Physics is a peer-reviewed international journal published by the Brazilian Physical Society (SBF). The journal publishes new and original research results from all areas of physics, obtained in Brazil and from anywhere else in the world. Contents include theoretical, practical and experimental papers as well as high-quality review papers. Submissions should follow the generally accepted structure for journal articles with basic elements: title, abstract, introduction, results, conclusions, and references.