ZnMoO4-TiO2 的介电性能和导电性能:探索高温性能和应用潜力

IF 1.5 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY
Subhangi Kalingani, Satyaprakash Narayan Das, Satyanaryan Bhuyan
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引用次数: 0

摘要

考虑到陶瓷工程的进步,本研究探讨了 ZnMoO4-TiO2 电子复合材料的合成。它是利用固态混合氧化物反应技术合成的。样品在 780 °C 煅烧,810 °C 烧结。样品结构的 X 射线衍射图样与 JCPDS 参考编码 98-000-4862 和 98-002-2025 一致。常温扫描电镜和 EDAX 揭示了材料的结构和成分。复合微观结构显示出连续的晶粒分散和独特的孔隙率。在 30 至 450 °C、1 千赫兹(kHz)至 1 兆赫兹(MHz)范围内,对介电强度、损耗正切和电导率进行了全面分析。温度高于 300 ℃ 时,介电常数增加。当温度从 400 ℃ 升至 450 ℃ 时,导电活化能呈现出不同的数值范围,在不同频率下具体为 0.82 至 1.92 eV。紫外可见光谱测定的带隙能为 3.12 eV,在 205 纳米和 390 纳米处有吸收峰。基于这些发现,ZnMoO4-TiO2 可能适用于湿度传感器和其他电子电气设备。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Dielectric and Conductive Properties of ZnMoO4-TiO2: Exploring High-Temperature Performance and Application Potential

Dielectric and Conductive Properties of ZnMoO4-TiO2: Exploring High-Temperature Performance and Application Potential

Considering ceramic engineering advances, this study explores ZnMoO4-TiO2 electronic composite synthesis. This is synthesized using a solid-state mixed oxide reaction technique. Sample is calcined at 780 °C and sintered at 810 °C. The X-ray diffraction pattern of the sample structure matches with the JCPDS reference codes 98–000-4862 and 98–002-2025. Ambient temperature SEM and EDAX reveal the material’s structure and composition. Compound microstructure exhibits continuous grain dispersion and unique porosity. Dielectric, loss tangent, and conductivity were comprehensively analyzed from 30 to 450 °C and 1 kilohertz (kHz) to 1 megahertz (MHz). At temperatures above 300 °C, the dielectric constant increases. The activation energy for electrical conductivity exhibits a range of values, specifically from 0.82 to 1.92 eV at various frequencies, when the temperature increases from 400 to 450 °C. UV–visible spectroscopy determined the band gap energy of 3.12 eV, with absorption peaks at 205 and 390 nm. Based on these findings, ZnMoO4-TiO2 may be suitable for humidity sensors and other electrical and electronic devices.

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来源期刊
Brazilian Journal of Physics
Brazilian Journal of Physics 物理-物理:综合
CiteScore
2.50
自引率
6.20%
发文量
189
审稿时长
6.0 months
期刊介绍: The Brazilian Journal of Physics is a peer-reviewed international journal published by the Brazilian Physical Society (SBF). The journal publishes new and original research results from all areas of physics, obtained in Brazil and from anywhere else in the world. Contents include theoretical, practical and experimental papers as well as high-quality review papers. Submissions should follow the generally accepted structure for journal articles with basic elements: title, abstract, introduction, results, conclusions, and references.
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