Influence of temperature and crack-tip speed on crack propagation in elastic solids

I study the influence of temperature and the crack-tip velocity of the bond breaking at the crack tip in rubber-like materials. The bond breaking is considered as a stress-aided thermally activated process and result in an effective crack propagation energy which increases strongly with decreasing temperature or increasing crack-tip speed. This effect is particular important for adhesive (interfacial) crack propagation but less important for cohesive crack propagation owing to the much larger bond-breaking energies in the latter case. For adhesive cracks the theory results are consistent with adhesion measurements for silicone (PDMS) rubber in contact with silica glass surfaces. For cohesive cracks the theory agree well with experimental results PDMS films chemically bound to silinized glass.