Daniel Lozano-Martín, Andres Rojo, M. Carmen Martín, David Vega-Maza, José Juan Segovia
{"title":"在 $T$ = (273.16 至 375) K 条件下,p$ = (0.5 至 20) MPa 的 ($CH_{4}$ + $He$) 混合物的声速","authors":"Daniel Lozano-Martín, Andres Rojo, M. Carmen Martín, David Vega-Maza, José Juan Segovia","doi":"arxiv-2409.08128","DOIUrl":null,"url":null,"abstract":"This work aims to provide accurate and wide-ranging experimental new speed of\nsound data $w$($p$,$T$) of two binary ($CH_{4}$ + $He$) mixtures at a nominal\nhelium content of 5% and 10% at pressures $p$ = (0.5 up to 20) MPa and\ntemperatures $T$ = (273.16, 300, 325, 350 and 375) K. For this purpose, the\nmost accurate technique for determining speed of sound in gas phase has been\nused: the spherical acoustic resonator. Speed of sound is determined with an\noverall relative expanded ($k$ = 2) uncertainty of 230 parts in $10^{6}$ and\ncompared to reference models for multicomponent natural gas-like mixtures:\nAGA8-DC92 and GERG-2008 equations of state. Relative deviations of experimental\ndata from model estimations are outside the experimental uncertainty limit,\nalthough all points are mostly within the AGA uncertainty of 0.2% and GERG\nuncertainty of 0.5% and worsen as the helium content increases. Absolute\naverage deviations are better than 0.45% for GERG and below 0.14% for AGA\nmodels in (0.95 $CH_{4}$ + 0.05 $He$) mixture and below 0.83% for GERG and\nwithin 0.22% for AGA equations in (0.90 $CH_{4}$ + 0.10 $He$) mixture.","PeriodicalId":501304,"journal":{"name":"arXiv - PHYS - Chemical Physics","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Speeds of sound for ($CH_{4}$ + $He$) mixtures from $p$ = (0.5 to 20) MPa at $T$ = (273.16 to 375) K\",\"authors\":\"Daniel Lozano-Martín, Andres Rojo, M. Carmen Martín, David Vega-Maza, José Juan Segovia\",\"doi\":\"arxiv-2409.08128\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"This work aims to provide accurate and wide-ranging experimental new speed of\\nsound data $w$($p$,$T$) of two binary ($CH_{4}$ + $He$) mixtures at a nominal\\nhelium content of 5% and 10% at pressures $p$ = (0.5 up to 20) MPa and\\ntemperatures $T$ = (273.16, 300, 325, 350 and 375) K. For this purpose, the\\nmost accurate technique for determining speed of sound in gas phase has been\\nused: the spherical acoustic resonator. Speed of sound is determined with an\\noverall relative expanded ($k$ = 2) uncertainty of 230 parts in $10^{6}$ and\\ncompared to reference models for multicomponent natural gas-like mixtures:\\nAGA8-DC92 and GERG-2008 equations of state. Relative deviations of experimental\\ndata from model estimations are outside the experimental uncertainty limit,\\nalthough all points are mostly within the AGA uncertainty of 0.2% and GERG\\nuncertainty of 0.5% and worsen as the helium content increases. Absolute\\naverage deviations are better than 0.45% for GERG and below 0.14% for AGA\\nmodels in (0.95 $CH_{4}$ + 0.05 $He$) mixture and below 0.83% for GERG and\\nwithin 0.22% for AGA equations in (0.90 $CH_{4}$ + 0.10 $He$) mixture.\",\"PeriodicalId\":501304,\"journal\":{\"name\":\"arXiv - PHYS - Chemical Physics\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-09-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"arXiv - PHYS - Chemical Physics\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/arxiv-2409.08128\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"arXiv - PHYS - Chemical Physics","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/arxiv-2409.08128","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Speeds of sound for ($CH_{4}$ + $He$) mixtures from $p$ = (0.5 to 20) MPa at $T$ = (273.16 to 375) K
This work aims to provide accurate and wide-ranging experimental new speed of
sound data $w$($p$,$T$) of two binary ($CH_{4}$ + $He$) mixtures at a nominal
helium content of 5% and 10% at pressures $p$ = (0.5 up to 20) MPa and
temperatures $T$ = (273.16, 300, 325, 350 and 375) K. For this purpose, the
most accurate technique for determining speed of sound in gas phase has been
used: the spherical acoustic resonator. Speed of sound is determined with an
overall relative expanded ($k$ = 2) uncertainty of 230 parts in $10^{6}$ and
compared to reference models for multicomponent natural gas-like mixtures:
AGA8-DC92 and GERG-2008 equations of state. Relative deviations of experimental
data from model estimations are outside the experimental uncertainty limit,
although all points are mostly within the AGA uncertainty of 0.2% and GERG
uncertainty of 0.5% and worsen as the helium content increases. Absolute
average deviations are better than 0.45% for GERG and below 0.14% for AGA
models in (0.95 $CH_{4}$ + 0.05 $He$) mixture and below 0.83% for GERG and
within 0.22% for AGA equations in (0.90 $CH_{4}$ + 0.10 $He$) mixture.