在 $T$ = (273.16 至 375) K 条件下,p$ = (0.5 至 20) MPa 的 ($CH_{4}$ + $He$) 混合物的声速

Daniel Lozano-Martín, Andres Rojo, M. Carmen Martín, David Vega-Maza, José Juan Segovia
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引用次数: 0

摘要

这项工作旨在提供两种二元($CH_{4}$ + $He$)混合物在标称氦含量为 5%和 10%、压力为 p$ = (0.5 至 20) MPa 和温度为 T$ = (273.16, 300, 325, 350 和 375) K 时的精确和广泛的新声速实验数据 $w$($p$,$T$)。声速的测定结果与多组分天然气类混合物的参考模型 AGA8-DC92 和 GERG-2008 状态方程相比较,总体相对扩展(k$=2)不确定度为 230 分之 10^{6}$ 。实验数据与模型估计值的相对偏差在实验不确定性限制之外,尽管所有点大部分都在 AGA 不确定性 0.2% 和 GERG 不确定性 0.5% 的范围内,并且随着氦含量的增加而恶化。在(0.95 $CH_{4}$ + 0.05 $He$)混合物中,GERG 的绝对平均偏差优于 0.45%,AGA 模型的绝对平均偏差低于 0.14%;在(0.90 $CH_{4}$ + 0.10 $He$)混合物中,GERG 的绝对平均偏差低于 0.83%,AGA 方程的绝对平均偏差低于 0.22%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Speeds of sound for ($CH_{4}$ + $He$) mixtures from $p$ = (0.5 to 20) MPa at $T$ = (273.16 to 375) K
This work aims to provide accurate and wide-ranging experimental new speed of sound data $w$($p$,$T$) of two binary ($CH_{4}$ + $He$) mixtures at a nominal helium content of 5% and 10% at pressures $p$ = (0.5 up to 20) MPa and temperatures $T$ = (273.16, 300, 325, 350 and 375) K. For this purpose, the most accurate technique for determining speed of sound in gas phase has been used: the spherical acoustic resonator. Speed of sound is determined with an overall relative expanded ($k$ = 2) uncertainty of 230 parts in $10^{6}$ and compared to reference models for multicomponent natural gas-like mixtures: AGA8-DC92 and GERG-2008 equations of state. Relative deviations of experimental data from model estimations are outside the experimental uncertainty limit, although all points are mostly within the AGA uncertainty of 0.2% and GERG uncertainty of 0.5% and worsen as the helium content increases. Absolute average deviations are better than 0.45% for GERG and below 0.14% for AGA models in (0.95 $CH_{4}$ + 0.05 $He$) mixture and below 0.83% for GERG and within 0.22% for AGA equations in (0.90 $CH_{4}$ + 0.10 $He$) mixture.
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