用于高性能 Zn 离子混合电容器的富氮纳米多孔碳与 MXene 复合材料

IF 9 2区 材料科学 Q1 CHEMISTRY, PHYSICAL
Doudou Zhao, Da Xu, Tiantian Wang, Zhenglong Yang
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引用次数: 0

摘要

锌-离子混合电容器作为一种新型储能系统,具有优异的电化学性能、低成本和高安全性,引起了广泛的研究关注。在这项工作中,我们报告了一种异质结构复合材料 CN@MXene,它是由多孔碳材料 CN 与 MXene 纳米片交替堆叠而成。理论计算和一系列表征结果表明,MXene 纳米片的引入不仅暴露了 CN 的更多活性位点,还显著增强了整个复合材料的导电性和稳定性,从而实现了优异的电化学储能性能。因此,作为锌离子混合电容器的阴极材料,CN @MXene 在 0.1 A/g 时可实现 240 mA h/g 的高比容量,并在 1 至 20 A/g 的范围内表现出优异的速率性能。在 5 A/g 的电流密度下,经过 10,000 次充放电循环后,电容保持率仍高达 94%。此外,在 CN @MXene 电极的基础上,利用激光切割技术制造出了具有 264 mF/cm 高面积比容量的柔性锌离子微电容器。我们相信,这项工作为开发高性能锌离子混合电容器提供了新的研究策略。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Nitrogen-rich nanoporous carbon with MXene composite for high-performance Zn-ion hybrid capacitors
The zinc-ion hybrid capacitor, as a novel energy storage system with outstanding electrochemical performance, low cost, and high safety, has attracted widespread research attention. In this work, we report a hetero-structured composite material, CN@MXene, obtained by alternately stacking porous carbon material CN with MXene nanosheets. Theoretical calculations and a series of characterizations reveal that the introduction of MXene nanosheets not only exposes more active sites of CN, but also significantly enhances the conductivity and stability of the overall composite material, thereby achieving excellent electrochemical energy storage performance. Consequently, as a cathode material for zinc-ion hybrid capacitors, CN @MXene achieves a high specific capacity of 240 mA h/g at 0.1 A/g and exhibits outstanding rate performance from 1 to 20 A/g. And the capacitance retention rate remains as high as 94%, after 10,000 cycles of charge-discharge at a current density of 5 A/g. Moreover, based on the CN @MXene electrode, flexible zinc ion micro-capacitor with high area-specific capacity of 264 mF/cm was fabricated using laser cutting technology. We believe that this work provides new research strategies for developing high-performance zinc-ion hybrid capacitors.
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来源期刊
Materials Today Energy
Materials Today Energy Materials Science-Materials Science (miscellaneous)
CiteScore
15.10
自引率
7.50%
发文量
291
审稿时长
15 days
期刊介绍: Materials Today Energy is a multi-disciplinary, rapid-publication journal focused on all aspects of materials for energy. Materials Today Energy provides a forum for the discussion of high quality research that is helping define the inclusive, growing field of energy materials. Part of the Materials Today family, Materials Today Energy offers authors rigorous peer review, rapid decisions, and high visibility. The editors welcome comprehensive articles, short communications and reviews on both theoretical and experimental work in relation to energy harvesting, conversion, storage and distribution, on topics including but not limited to: -Solar energy conversion -Hydrogen generation -Photocatalysis -Thermoelectric materials and devices -Materials for nuclear energy applications -Materials for Energy Storage -Environment protection -Sustainable and green materials
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