{"title":"用铁硼化物增强的双层复合涂料","authors":"O. V. Sukhova","doi":"10.1007/s11106-024-00428-2","DOIUrl":null,"url":null,"abstract":"<p>The furnace infiltration technique was proposed to produce two-layer macroheterogeneous composite coatings. The technique involved consecutive infiltration of hard alloy reinforcement granules with two metallic matrices differing in the melting point. The infiltration resulted in a twolayer composite coating, with the layers being strengthened with the same reinforcement but not having the same matrix compositions. The Fe–12.5% B–0.1% C alloy was used as the reinforcement and the L62 copper-based alloy or hypoeutectic Fe–3.5% B–0.2% C alloy was the matrix. Quantitative metallography, energy-dispersive microanalysis, and microhardness measurements were employed to examine the structurization of interfaces between the boride reinforcement and the molten matrices. Furnace infiltration ensured virtually defect-free structure of the two-layer composite coating, with porosity not exceeding 5 to 7%. This was achieved through the dissolution of reinforcement surface phases in the molten matrices during infiltration without forming brittle intermetallic phases at the interfaces. The intensity of contact interaction processes at the interfaces between iron borides and iron- and copper-based matrices was compared. The mechanical and performance properties of the composite coating layers were studied. The combination of two layers prevented the delamination of the composite coatings under nonuniform distribution of temperatures, stresses, and strains. 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引用次数: 0
摘要
有人提出用熔炉渗透技术来生产双层宏观异质复合涂层。该技术包括将硬质合金强化颗粒与两种熔点不同的金属基体连续浸润。浸润后可形成双层复合涂层,各层增强材料相同,但基体成分不同。强化层采用 Fe-12.5% B-0.1% C 合金,基体采用 L62 铜基合金或低共晶 Fe-3.5% B-0.2% C 合金。定量金相分析、能量色散显微分析和显微硬度测量被用来检查硼化物增强材料与熔融基体之间的界面结构。熔炉渗透确保了双层复合涂层的结构几乎没有缺陷,孔隙率不超过 5%至 7%。这是由于在浸润过程中,熔融基质中的增强体表面相溶解,而不会在界面上形成脆性金属间相。比较了铁硼化物与铁基和铜基基材界面接触相互作用过程的强度。研究了复合涂层的机械性能和性能。在温度、应力和应变分布不均匀的情况下,两层涂层的结合防止了复合涂层的分层。这决定了将所提出的技术用于航空航天工程零件表面强化的前景。
Two-Layer Composite Coatings Reinforced with Iron Borides
The furnace infiltration technique was proposed to produce two-layer macroheterogeneous composite coatings. The technique involved consecutive infiltration of hard alloy reinforcement granules with two metallic matrices differing in the melting point. The infiltration resulted in a twolayer composite coating, with the layers being strengthened with the same reinforcement but not having the same matrix compositions. The Fe–12.5% B–0.1% C alloy was used as the reinforcement and the L62 copper-based alloy or hypoeutectic Fe–3.5% B–0.2% C alloy was the matrix. Quantitative metallography, energy-dispersive microanalysis, and microhardness measurements were employed to examine the structurization of interfaces between the boride reinforcement and the molten matrices. Furnace infiltration ensured virtually defect-free structure of the two-layer composite coating, with porosity not exceeding 5 to 7%. This was achieved through the dissolution of reinforcement surface phases in the molten matrices during infiltration without forming brittle intermetallic phases at the interfaces. The intensity of contact interaction processes at the interfaces between iron borides and iron- and copper-based matrices was compared. The mechanical and performance properties of the composite coating layers were studied. The combination of two layers prevented the delamination of the composite coatings under nonuniform distribution of temperatures, stresses, and strains. This determines the prospects of using the proposed technique for surface strengthening of aerospace engineering parts.
期刊介绍:
Powder Metallurgy and Metal Ceramics covers topics of the theory, manufacturing technology, and properties of powder; technology of forming processes; the technology of sintering, heat treatment, and thermo-chemical treatment; properties of sintered materials; and testing methods.