微波干燥过程对 Y2O3-Al2O3-ZrO2 复合陶瓷粉末物理性质的实验研究与统计分析

Mingshuang Duan, Chunxiao Ren, Na Zheng, Mamdouh Omran, Ju Tang, Fan Zhang, Guo Chen
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摘要

YO-AlO-ZrO 复合陶瓷粉末是一种重要的结构和功能材料。要制备高质量的陶瓷粉末,必须解决陶瓷粉末干燥过程中的团聚问题,而选择正确的干燥技术可以显著减少陶瓷粉末的团聚。利用微波干燥技术干燥了 YO-AlO-ZrO 陶瓷粉末。粉末的干燥动力学随其初始质量、含水量和微波功率而变化。根据实验数据,随着微波功率、初始含水量和初始质量的增加,平均干燥速率也随之增加。为了更好地描述微波干燥过程,使用四种薄层干燥动力学模型对干燥数据进行了拟合和分析,即二次模型、修正佩奇模型、王和辛格模型以及二项指数模型。结果表明,修正佩奇模型的拟合效果良好,拟合参数符合规律。通过傅立叶变换红外光谱对干燥前后的样品进行了表征。根据菲克第二定律计算扩散系数可知,当初始含水率为 5%、微波加热功率为 560 W、初始质量为 25 g 时,YO-AlO-ZrO 复合陶瓷粉末的有效扩散系数为 5.6 × 10 m/s;根据阿伦尼乌斯公式计算出 YO-AlO-ZrO 陶瓷粉末微波干燥的活化能为 22.83 W/g。本文旨在为研究 YO-AlO-ZrO 复合陶瓷粉末的微波干燥提供理论依据和丰富的实验数据。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Experimental investigation and statistical analysis of the microwave drying process on the physical properties of Y2O3–Al2O3–ZrO2 composite ceramic powder
YO–AlO–ZrO composite ceramic powders are an important structural and functional material. The agglomeration problem in the ceramic powder drying process must be resolved to prepare high-quality ceramic powder, and choosing the right drying techniques can significantly lessen ceramic powder agglomeration. YO–AlO–ZrO ceramic powder was dried using microwave drying. The drying kinetics of the powders were examined with their initial mass, moisture content, and microwave power. As microwave power, beginning moisture content, and initial mass rose, the average drying rate also increased, according to the experimental data. To better characterize the microwave drying process, the drying data were fitted and analyzed using four thin-layer drying kinetic models, namely Quadratic Model, Modified Page, Wang and Singh, and Two-term exponential. The outcomes demonstrate the good fitting effect of the Modified Page model and the compliance of the fitting parameters with the law. The samples before and after drying were characterized by Fourier transform infrared spectroscopy. Calculating the diffusion coefficient by Fick's second law shows that the effective diffusion coefficient of YO–AlO–ZrO composite ceramic powder is 5.6 × 10 m/s when the initial moisture content is 5%, the microwave heating power is 560 W, and the initial mass is 25 g. The activation energy for microwave drying of YO–AlO–ZrO ceramic powders was calculated to be 22.83 W/g according to the Arrhenius formula. This paper aims to provide a theoretical basis and rich experimental data for the study of microwave drying of YO–AlO–ZrO composite ceramic powder.
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