实现功能性光学材料的有机电荷转移复合物

IF 2.6 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
CrystEngComm Pub Date : 2024-08-13 DOI:10.1039/D4CE00701H
Kalyan Jyoti Kalita, Rakhi Arikkottira M and Ratheesh K. Vijayaraghavan
{"title":"实现功能性光学材料的有机电荷转移复合物","authors":"Kalyan Jyoti Kalita, Rakhi Arikkottira M and Ratheesh K. Vijayaraghavan","doi":"10.1039/D4CE00701H","DOIUrl":null,"url":null,"abstract":"<p >This year marks the 50th anniversary of a significant milestone in organic optoelectronics, <em>i.e.</em>, the first account of metallic-like conductivity in an entirely organic material, tetrathiafulvalene–tetracyanoquinodimethane (TTF–TCNQ). Since the discovery of this prototypical TTF–TCNQ charge-transfer (CT) pair, countless studies, ranging from various aspects, have been done on this fascinating TTF–TCNQ and related CT complexes. More recently, the CT complex-based approach has emerged as an elegant way of designing various next-generation functional organic materials, <em>viz.</em> room temperature phosphorescent (RTP), thermally activated delayed fluorescent (TADF), near infra infrared (NIR) emissive, organic spin-systems, <em>etc.</em> This highlight discusses how the synergy between computational screening and crystal engineering principles can be used to obtain the desired functional output and modulate the CT complex's bulk optical and electronic features. Emphasis is given to some of the recent non-covalent CT complex-based approaches to designing functional optical materials like RTP, TADF, NIR-emissive, chiral CT complex, <em>etc.</em></p>","PeriodicalId":70,"journal":{"name":"CrystEngComm","volume":" 35","pages":" 4751-4765"},"PeriodicalIF":2.6000,"publicationDate":"2024-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Organic charge transfer complex towards functional optical materials\",\"authors\":\"Kalyan Jyoti Kalita, Rakhi Arikkottira M and Ratheesh K. Vijayaraghavan\",\"doi\":\"10.1039/D4CE00701H\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >This year marks the 50th anniversary of a significant milestone in organic optoelectronics, <em>i.e.</em>, the first account of metallic-like conductivity in an entirely organic material, tetrathiafulvalene–tetracyanoquinodimethane (TTF–TCNQ). Since the discovery of this prototypical TTF–TCNQ charge-transfer (CT) pair, countless studies, ranging from various aspects, have been done on this fascinating TTF–TCNQ and related CT complexes. More recently, the CT complex-based approach has emerged as an elegant way of designing various next-generation functional organic materials, <em>viz.</em> room temperature phosphorescent (RTP), thermally activated delayed fluorescent (TADF), near infra infrared (NIR) emissive, organic spin-systems, <em>etc.</em> This highlight discusses how the synergy between computational screening and crystal engineering principles can be used to obtain the desired functional output and modulate the CT complex's bulk optical and electronic features. Emphasis is given to some of the recent non-covalent CT complex-based approaches to designing functional optical materials like RTP, TADF, NIR-emissive, chiral CT complex, <em>etc.</em></p>\",\"PeriodicalId\":70,\"journal\":{\"name\":\"CrystEngComm\",\"volume\":\" 35\",\"pages\":\" 4751-4765\"},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2024-08-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"CrystEngComm\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2024/ce/d4ce00701h\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"CrystEngComm","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/ce/d4ce00701h","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

今年是有机光电子学的一个重要里程碑,即首次在一种完全有机的材料--四硫富戊烯-四氰醌二甲烷(TTF-TCNQ)--中发现类似金属的导电性的 50 周年。自从发现这种典型的 TTF-TCNQ 电荷转移(CT)对以来,人们从各个方面对这种迷人的 TTF-TCNQ 和相关 CT 复合物进行了无数的研究。最近,基于 CT 复合物的方法已成为设计各种下一代功能有机材料(即室温磷光 (RTP)、热激活延迟荧光 (TADF)、近红外 (NIR) 发射、有机自旋系统等)的一种优雅方法。本重点讨论如何利用计算筛选和晶体工程原理之间的协同作用来获得所需的功能输出,并调节 CT 复合物的体光学和电子特性。重点介绍最近一些基于非共价 CT 复合物设计功能光学材料的方法,如 RTP、TADF、近红外发射、手性 CT 复合物等。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Organic charge transfer complex towards functional optical materials

Organic charge transfer complex towards functional optical materials

This year marks the 50th anniversary of a significant milestone in organic optoelectronics, i.e., the first account of metallic-like conductivity in an entirely organic material, tetrathiafulvalene–tetracyanoquinodimethane (TTF–TCNQ). Since the discovery of this prototypical TTF–TCNQ charge-transfer (CT) pair, countless studies, ranging from various aspects, have been done on this fascinating TTF–TCNQ and related CT complexes. More recently, the CT complex-based approach has emerged as an elegant way of designing various next-generation functional organic materials, viz. room temperature phosphorescent (RTP), thermally activated delayed fluorescent (TADF), near infra infrared (NIR) emissive, organic spin-systems, etc. This highlight discusses how the synergy between computational screening and crystal engineering principles can be used to obtain the desired functional output and modulate the CT complex's bulk optical and electronic features. Emphasis is given to some of the recent non-covalent CT complex-based approaches to designing functional optical materials like RTP, TADF, NIR-emissive, chiral CT complex, etc.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
CrystEngComm
CrystEngComm 化学-化学综合
CiteScore
5.50
自引率
9.70%
发文量
747
审稿时长
1.7 months
期刊介绍: Design and understanding of solid-state and crystalline materials
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信