基于银纳米颗粒和线性硅基流体的聚光太阳能高效纳米流体

IF 5.3 2区 化学 Q2 CHEMISTRY, PHYSICAL
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引用次数: 0

摘要

提高可再生能源的效率可以以环保的方式获取电能。因此,开发用于聚光太阳能抛物面槽式集热器(CSP-PTC)的纳米流体是一个值得关注的研究方向。因此,在这项工作中,制备了基于银纳米颗粒的纳米流体和用于 CSP-PTC 技术的聚二甲基硅氧烷(PDMS)型流体。这种流体在该技术中的使用和基于它的纳米流体的制备尚未得到广泛研究,因此对使用这种流体制备的纳米流体进行评估是非常有意义的。因此,对物理稳定性和所测量的相关特性(即密度、表面张力、粘度、等压比热和导热性)进行了表征。制备的纳米流体具有有趣的热特性。与基础流体相比,等压比热增加了 4.5%,热导率增加了 24%,而粘度没有显著增加。因此,传热系数最高提高了 16%。这些结果对于在 CSP-PTC 技术中使用所制备的纳米流体确实很有希望。最后,等压比热的适度增加和热传导率的显著提高是由于在银表面和 PDMS 分子之间观察到了微弱的范德华力相互作用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Efficient nanofluids based on Ag nanoparticles and a linear silicone-based fluid for concentrating solar power

Efficient nanofluids based on Ag nanoparticles and a linear silicone-based fluid for concentrating solar power

Improving the efficiency of renewable energy sources can lead to obtaining electrical energy in an environmentally-friendly way. Therefore, the development of nanofluids for use in parabolic trough collectors in concentrated solar energy (CSP-PTC) is a research line of interest. Thus, in this work, nanofluids based on Ag nanoparticles and a polydimethylsiloxane (PDMS) type fluid used in CSP-PTC technology were prepared. The use of this fluid in this technology and the preparation of nanofluids based on it has not been studied widely, and the evaluation of the use of nanofluids from this type fluid is of great interest. Thus, the physical stability and the properties of interest measured, that are density, surface tension, viscosity, isobaric specific heat and thermal conductivity, were characterized. The nanofluids prepared presented interesting thermal properties. An increase of up to 4.5 % in the isobaric specific heat and up to 24 % in thermal conductivity were observed with respect to the base fluid, without a significant increase in viscosity. Thus, an increase in the heat transfer coefficient of up to 16 % was obtained. These results are really promising for the use of the nanofluids prepared in CSP-PTC technology. Finally, the moderate increase in isobaric specific heat and the significant increase in thermal conductivity is explained by the weak Van der Waals force interaction observed between the Ag surfaces and the PDMS molecules.

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来源期刊
Journal of Molecular Liquids
Journal of Molecular Liquids 化学-物理:原子、分子和化学物理
CiteScore
10.30
自引率
16.70%
发文量
2597
审稿时长
78 days
期刊介绍: The journal includes papers in the following areas: – Simple organic liquids and mixtures – Ionic liquids – Surfactant solutions (including micelles and vesicles) and liquid interfaces – Colloidal solutions and nanoparticles – Thermotropic and lyotropic liquid crystals – Ferrofluids – Water, aqueous solutions and other hydrogen-bonded liquids – Lubricants, polymer solutions and melts – Molten metals and salts – Phase transitions and critical phenomena in liquids and confined fluids – Self assembly in complex liquids.– Biomolecules in solution The emphasis is on the molecular (or microscopic) understanding of particular liquids or liquid systems, especially concerning structure, dynamics and intermolecular forces. The experimental techniques used may include: – Conventional spectroscopy (mid-IR and far-IR, Raman, NMR, etc.) – Non-linear optics and time resolved spectroscopy (psec, fsec, asec, ISRS, etc.) – Light scattering (Rayleigh, Brillouin, PCS, etc.) – Dielectric relaxation – X-ray and neutron scattering and diffraction. Experimental studies, computer simulations (MD or MC) and analytical theory will be considered for publication; papers just reporting experimental results that do not contribute to the understanding of the fundamentals of molecular and ionic liquids will not be accepted. Only papers of a non-routine nature and advancing the field will be considered for publication.
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