Revisiting the formation of lunar anorthosites via the RbSr isotope systematics

The incorporation of KREEP (potassium, rare-earth element, and phosphorus), mantle-derived mafic melts and trapped liquid into the lunar ferroan anorthosite (FAN) suite plays a pivotal role in generating their geochemical and isotopic variations. Nonetheless, the specific involvement and distinct roles of these different components remain controversial. This study presents in-situ Sr isotopic data for 28 anorthositic clasts found within lunar feldspathic meteorites to trace their sources and post-modification processes. We find that these plagioclases exhibit substantial variations in their measured ⁸⁷Sr/⁸⁶Sr values (0.69978–0.70357), in contrast to the relatively narrow range observed in Apollo 16 FANs, thereby likely reflecting a diverse chemical composition of lunar crustal rocks. In contrast, the analyzed plagioclases have consistently low ⁸⁷Rb/⁸⁶Sr ratios (0.00185–0.03962), similar to those of Apollo samples, reflecting impact-induced loss of Rb. Detailed investigations indicate that certain elevated ⁸⁷Sr/⁸⁶Sr ratios are probably not caused by terrestrial contamination or instrumental analysis, but most likely result from the decay of ⁸⁷Rb from sources with initial ⁸⁷Rb/⁸⁶Sr higher than 0.0119–0.1380. However, such elevated ⁸⁷Rb/⁸⁶Sr values cannot solely result from crystallization of the lunar magma ocean (LMO) and likely involve KREEP components. Combined with trace element data, we estimate the maximum proportion of KREEP melt in the formation of lunar anorthosites. Future analyses of lunar anorthosites collected by China's Chang'e-5 and Chang'e-6 missions will be crucial for validating the observed Sr isotopic heterogeneity.