{"title":"γ-氨基丁酸辅助制备板状 ZSM-5 沸石,用于高效生产甲醇制丙烯","authors":"","doi":"10.1016/j.apcata.2024.119912","DOIUrl":null,"url":null,"abstract":"<div><p>Plate-like ZSM-5 zeolites offering a short diffusion pathway along the <em>b-</em>axis are highly desirable catalyst for methanol to propylene (MTP) reaction. Herein, we successfully developed a simple synthetic strategy toward reducing the thickness along <em>b</em>-axis of ZSM-5 zeolite by combing a preliminary aging process and the addition of γ-aminobutyric acid. In particular, γ-aminobutyric acid adopted as a zeolite growth modifier was firstly proposed to prepare plate-like ZSM-5 zeolite with a short thickness of <em>b</em>-axis, and the minimum thickness can reach ∼50 nm. The shortened diffusion length in plate-like ZSM-5 zeolites could significantly improve the transport efficiency of molecules to and away from the active sites and finally leads to a better catalytic performance in the MTP reaction. Particularly, the plate-like ZSM-5 zeolite with an impressively shortened diffusion length (P-ZSM-5–0.3#0.3) displayed greatly improved catalytic performances (higher propylene selectivity and longer lifetime) than conventional ZSM-5 with a thicker dimension along the <em>b</em>-axis.</p></div>","PeriodicalId":243,"journal":{"name":"Applied Catalysis A: General","volume":null,"pages":null},"PeriodicalIF":4.7000,"publicationDate":"2024-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"γ-aminobutyric acid-assisted fabrication of plate-like ZSM-5 zeolite for efficient propylene production from methanol conversion\",\"authors\":\"\",\"doi\":\"10.1016/j.apcata.2024.119912\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Plate-like ZSM-5 zeolites offering a short diffusion pathway along the <em>b-</em>axis are highly desirable catalyst for methanol to propylene (MTP) reaction. Herein, we successfully developed a simple synthetic strategy toward reducing the thickness along <em>b</em>-axis of ZSM-5 zeolite by combing a preliminary aging process and the addition of γ-aminobutyric acid. In particular, γ-aminobutyric acid adopted as a zeolite growth modifier was firstly proposed to prepare plate-like ZSM-5 zeolite with a short thickness of <em>b</em>-axis, and the minimum thickness can reach ∼50 nm. The shortened diffusion length in plate-like ZSM-5 zeolites could significantly improve the transport efficiency of molecules to and away from the active sites and finally leads to a better catalytic performance in the MTP reaction. Particularly, the plate-like ZSM-5 zeolite with an impressively shortened diffusion length (P-ZSM-5–0.3#0.3) displayed greatly improved catalytic performances (higher propylene selectivity and longer lifetime) than conventional ZSM-5 with a thicker dimension along the <em>b</em>-axis.</p></div>\",\"PeriodicalId\":243,\"journal\":{\"name\":\"Applied Catalysis A: General\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":4.7000,\"publicationDate\":\"2024-08-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Catalysis A: General\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0926860X24003570\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Catalysis A: General","FirstCategoryId":"1","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0926860X24003570","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
摘要
板状 ZSM-5 沸石沿 b 轴的扩散路径较短,是甲醇制丙烯(MTP)反应非常理想的催化剂。在此,我们成功地开发了一种简单的合成策略,通过结合初步老化过程和添加γ-氨基丁酸来减少 ZSM-5 沸石沿 b 轴的厚度。其中,首次提出采用γ-氨基丁酸作为沸石生长改性剂,制备出b轴厚度较短的板状ZSM-5沸石,最小厚度可达∼50 nm。板状 ZSM-5 沸石中扩散长度的缩短可显著提高分子进出活性位点的传输效率,从而在 MTP 反应中获得更好的催化性能。尤其是扩散长度明显缩短的板状 ZSM-5 沸石(P-ZSM-5-0.3#0.3),其催化性能(更高的丙烯选择性和更长的使用寿命)比沿 b 轴尺寸较厚的传统 ZSM-5 大幅提高。
γ-aminobutyric acid-assisted fabrication of plate-like ZSM-5 zeolite for efficient propylene production from methanol conversion
Plate-like ZSM-5 zeolites offering a short diffusion pathway along the b-axis are highly desirable catalyst for methanol to propylene (MTP) reaction. Herein, we successfully developed a simple synthetic strategy toward reducing the thickness along b-axis of ZSM-5 zeolite by combing a preliminary aging process and the addition of γ-aminobutyric acid. In particular, γ-aminobutyric acid adopted as a zeolite growth modifier was firstly proposed to prepare plate-like ZSM-5 zeolite with a short thickness of b-axis, and the minimum thickness can reach ∼50 nm. The shortened diffusion length in plate-like ZSM-5 zeolites could significantly improve the transport efficiency of molecules to and away from the active sites and finally leads to a better catalytic performance in the MTP reaction. Particularly, the plate-like ZSM-5 zeolite with an impressively shortened diffusion length (P-ZSM-5–0.3#0.3) displayed greatly improved catalytic performances (higher propylene selectivity and longer lifetime) than conventional ZSM-5 with a thicker dimension along the b-axis.
期刊介绍:
Applied Catalysis A: General publishes original papers on all aspects of catalysis of basic and practical interest to chemical scientists in both industrial and academic fields, with an emphasis onnew understanding of catalysts and catalytic reactions, new catalytic materials, new techniques, and new processes, especially those that have potential practical implications.
Papers that report results of a thorough study or optimization of systems or processes that are well understood, widely studied, or minor variations of known ones are discouraged. Authors should include statements in a separate section "Justification for Publication" of how the manuscript fits the scope of the journal in the cover letter to the editors. Submissions without such justification will be rejected without review.