Strengthening Ti3SiC2/Cu brazed joint assisted with cold spray additive manufacturing: Lower brazing temperature through interdiffusion and graded reinforcement for stress relaxation

Graded composite fillers exhibit unique advantages in alleviating residual stress in ceramic/metal brazed joints. However, traditional methods for preparing graded composite fillers are often complex and may deplete their strengthening phases. In this study, cold spray additive manufacturing was employed to fabricate yttria-stabilized zirconia (YSZ)-Ti₂₅Zr₂₅Ni₂₅Cu₂₅-Ag graded composite coatings on Cu substrates to serve as fillers. The graded composite coatings and the resultant Ti₃SiC₂/Cu brazed joints were systematically characterized to elucidate the deposition mechanism of the coatings and its residual stress-relaxed mechanism. The bondings between particles in the coatings, based on their plastic deformation ability, were classified into noncrystalline weak bonds and homogeneous strong bonds. Both bondings facilitated the elemental interdiffusion between filler and Cu substrate during the heating process, which contributed to the formation of Ag-Cu eutectic. This significantly reduced the required brazing temperature and its induced residual stress. Furthermore, the solid phase transformation of graded-distributed YSZ within the brazing seam from tetragonal to monoclinic achieved a smooth thermal transition and releasing residual stress at the same time. Consequently, the shear strength of the brazed joint reached to the highest value of 110.23 ± 3.45 MPa, which was Much higher than the previously reported values. This study introduces a novel method for residual stress relaxation assisted with cold spray technology and broadens its application in the brazing field.