{"title":"经 g-C3N4 修饰的 Ag3PO4 光催化剂在盐酸四环素降解中的合成与应用","authors":"Jing Yang, Haixin Yang, Meng Li, Hongxi Zhang, Liang Wei, Xiande Yang","doi":"10.1016/j.solidstatesciences.2024.107654","DOIUrl":null,"url":null,"abstract":"<div><p>Finding highly efficient photocatalysts has practical significance for antibiotics degradation. In this work, g-C<sub>3</sub>N<sub>4</sub> modified Ag<sub>3</sub>PO<sub>4</sub> had been prepared via in-situ deposition method. Their photocatalytic activities were investigated through tetracycline hydrochloride (TCH) degradation under visible light. In summary, sample 6 wt% g-C<sub>3</sub>N<sub>4</sub>/Ag<sub>3</sub>PO<sub>4</sub> (6 wt% CN/APO) exhibited a good degradation efficiency (72.1 %) to TCH within 30 min, while pure Ag<sub>3</sub>PO<sub>4</sub> and g-C<sub>3</sub>N<sub>4</sub> was only 57.4 % and 5.8 %, respectively. Because of the construction of heterojunction structure, 6 wt% CN/APO composite had low fluorescence intensity, high photocurrent density and low resistance, which were helpful for the rapid separation of photogenerated carriers. Therefore, the photocatalytic property of Ag<sub>3</sub>PO<sub>4</sub> was obviously enhanced. In addition, sample 6 wt% CN/APO also showed excellent photocatalytic stability, and h<sup>+</sup> played a main role in TCH degradation. Its possible photocatalytic mechanism was also elucidated.</p></div>","PeriodicalId":432,"journal":{"name":"Solid State Sciences","volume":"155 ","pages":"Article 107654"},"PeriodicalIF":3.4000,"publicationDate":"2024-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and application of Ag3PO4 photocatalyst modified by g-C3N4 for tetracycline hydrochloride degradation\",\"authors\":\"Jing Yang, Haixin Yang, Meng Li, Hongxi Zhang, Liang Wei, Xiande Yang\",\"doi\":\"10.1016/j.solidstatesciences.2024.107654\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Finding highly efficient photocatalysts has practical significance for antibiotics degradation. In this work, g-C<sub>3</sub>N<sub>4</sub> modified Ag<sub>3</sub>PO<sub>4</sub> had been prepared via in-situ deposition method. Their photocatalytic activities were investigated through tetracycline hydrochloride (TCH) degradation under visible light. In summary, sample 6 wt% g-C<sub>3</sub>N<sub>4</sub>/Ag<sub>3</sub>PO<sub>4</sub> (6 wt% CN/APO) exhibited a good degradation efficiency (72.1 %) to TCH within 30 min, while pure Ag<sub>3</sub>PO<sub>4</sub> and g-C<sub>3</sub>N<sub>4</sub> was only 57.4 % and 5.8 %, respectively. Because of the construction of heterojunction structure, 6 wt% CN/APO composite had low fluorescence intensity, high photocurrent density and low resistance, which were helpful for the rapid separation of photogenerated carriers. Therefore, the photocatalytic property of Ag<sub>3</sub>PO<sub>4</sub> was obviously enhanced. In addition, sample 6 wt% CN/APO also showed excellent photocatalytic stability, and h<sup>+</sup> played a main role in TCH degradation. Its possible photocatalytic mechanism was also elucidated.</p></div>\",\"PeriodicalId\":432,\"journal\":{\"name\":\"Solid State Sciences\",\"volume\":\"155 \",\"pages\":\"Article 107654\"},\"PeriodicalIF\":3.4000,\"publicationDate\":\"2024-08-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Solid State Sciences\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S129325582400219X\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Solid State Sciences","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S129325582400219X","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Synthesis and application of Ag3PO4 photocatalyst modified by g-C3N4 for tetracycline hydrochloride degradation
Finding highly efficient photocatalysts has practical significance for antibiotics degradation. In this work, g-C3N4 modified Ag3PO4 had been prepared via in-situ deposition method. Their photocatalytic activities were investigated through tetracycline hydrochloride (TCH) degradation under visible light. In summary, sample 6 wt% g-C3N4/Ag3PO4 (6 wt% CN/APO) exhibited a good degradation efficiency (72.1 %) to TCH within 30 min, while pure Ag3PO4 and g-C3N4 was only 57.4 % and 5.8 %, respectively. Because of the construction of heterojunction structure, 6 wt% CN/APO composite had low fluorescence intensity, high photocurrent density and low resistance, which were helpful for the rapid separation of photogenerated carriers. Therefore, the photocatalytic property of Ag3PO4 was obviously enhanced. In addition, sample 6 wt% CN/APO also showed excellent photocatalytic stability, and h+ played a main role in TCH degradation. Its possible photocatalytic mechanism was also elucidated.
期刊介绍:
Solid State Sciences is the journal for researchers from the broad solid state chemistry and physics community. It publishes key articles on all aspects of solid state synthesis, structure-property relationships, theory and functionalities, in relation with experiments.
Key topics for stand-alone papers and special issues:
-Novel ways of synthesis, inorganic functional materials, including porous and glassy materials, hybrid organic-inorganic compounds and nanomaterials
-Physical properties, emphasizing but not limited to the electrical, magnetical and optical features
-Materials related to information technology and energy and environmental sciences.
The journal publishes feature articles from experts in the field upon invitation.
Solid State Sciences - your gateway to energy-related materials.