用回收的利乐包®电极和对位醌甲醚制造的有机半导体器件

IF 2.9 3区 材料科学 Q2 MATERIALS SCIENCE, COATINGS & FILMS
Coatings Pub Date : 2024-08-07 DOI:10.3390/coatings14080998
María Elena Sánchez Vergara, Eva Alejandra Santillán Esquivel, Ricardo Ballinas-Indilí, Octavio Lozada-Flores, René Miranda-Ruvalcaba, Cecilio Álvarez-Toledano
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引用次数: 0

摘要

这项研究介绍了对醌甲醚(p-QMs)的合成,在对其进行化学表征后,利用高真空升华技术将其沉积为薄膜。利用扫描电子显微镜、原子力显微镜和 X 射线衍射技术对对醌甲脒薄膜的形态和结构进行了表征。此外,还利用紫外-可见光谱法研究了它们的光学行为,得到的间接跃迁光隙在 2.21-2.71 eV 范围内,表明 p-QMs 具有半导体行为。通过制造和评估刚性半导体器件的电学行为验证了上述结论,其中使用了掺氟氧化锡涂层玻璃片(FTO)作为阳极和基底。最后,作为一种新颖、生态和低成本的应用,用回收利乐包(Tetra Pak®)制成的基底和阳极取代了 FTO,从而产生了柔性半导体器件。虽然电流传输取决于 p-QMs 的类型、其结构中的取代基和形态,但衬底和阳极的种类也会影响器件的电气行为类型。这项电流-电压研究表明,以 4-Cl-Ph 为自由基的 p-QM2、以 4-Et2N-Ph 为自由基的 p-QM3 和以 5-(1,3-苯并二恶茂) 为自由基的 p-QM6 可作为半导体薄膜应用于光电子领域。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Organic Semiconductor Devices Fabricated with Recycled Tetra Pak®-Based Electrodes and para-Quinone Methides
This work presents the synthesis of para-quinone methides (p-QMs), which were deposited as films using the high vacuum sublimation technique after being chemically characterized. The p-QMs films were characterized morphologically and structurally using scanning electron microscopy, atomic force microscopy, and X-ray diffraction. In addition, their optical behavior was studied by means of ultraviolet–visible spectroscopy, and the optical gaps obtained were in the range of 2.21–2.71 eV for indirect transitions, indicating the semiconductor behavior of the p-QMs. The above was verified through the manufacture and evaluation of the electrical behavior of rigid semiconductor devices, in which fluorine-doped tin oxide-coated glass slides (FTO) were used as an anode and substrate. Finally, as an original, ecological, and low-cost application, the FTO was replaced by substrates and anodes made from recycled Tetra Pak®, generating flexible semiconductor devices. Although the electrical current transported depends on the type of p-QMs, the substituent in its structure, and the morphology, the kinds of substrate and anode also influence the type of electrical behavior of the device. This current–voltage study demonstrates that p-QM2 with 4-Cl-Ph as a radical, p-QM3 with 4-Et2N-Ph as a radical, and p-QM6 with 5-(1,3-benzodioxol) as a radical can be used in optoelectronics as semiconductor films.
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来源期刊
Coatings
Coatings Materials Science-Surfaces, Coatings and Films
CiteScore
5.00
自引率
11.80%
发文量
1657
审稿时长
1.4 months
期刊介绍: Coatings is an international, peer-reviewed open access journal of coatings and surface engineering. It publishes reviews, research articles, communications and technical notes. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. There is no restriction on the length of the papers. Full experimental and/or methodical details must be provided. There are, in addition, unique features of this journal: * manuscripts regarding research proposals and research ideas will be particularly welcomed * electronic files or software regarding the full details of the calculation and experimental procedure - if unable to be published in a normal way - can be deposited as supplementary material
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