利用低电负性元素的特性发展有机光反应

IF 3.3 3区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Bulletin of the Chemical Society of Japan Pub Date : 2024-08-07 DOI:10.1093/bulcsj/uoae080

Yuki Nagashima

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引用次数: 0

摘要

有机光反应作为获得基态动力学和/或热力学禁用产物的独特工具，受到了广泛关注。这些光反应主要基于使用高电负性元素，如碳（C）、氧（O）、氮（N）、卤素（F、Cl、Br 和 I）以及过渡金属。另一方面，我们对低电负性元素（如硼（B）、硅（Si）和锡（Sn））在激发态下的特性也很感兴趣，这些元素可以实现高活性和/或选择性的光诱导硼烷基化、硅烷基化和锡烷基化。在本文中，我们将重点介绍利用硼、硅和锡元素进行各种有机光反应的最新研究成果。

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Development of organic photoreactions utilizing the characteristics of elements with low electronegativity

Organic photoreactions have received much attention as unique tools to access kinetically and/or thermodynamically prohibited products in the ground state. These photoreactions have been based mainly on using elements with high electronegativity such as carbon (C), oxygen (O), nitrogen (N), halogens (F, Cl, Br, and I) as well as transition metals. On the other hand, we have been interested in the characteristics of elements with low electronegativity, such as boron (B), silicon (Si), and tin (Sn), in the excited state, enabling highly reactive and/or selective photoinduced borylations, silylations, and stannylations. In this account, we highlight our latest findings concerning diverse organic photoreactions utilizing B, Si, and Sn elements, which are challenging when using conventional strategies.

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来源期刊

Bulletin of the Chemical Society of Japan 化学-化学综合

CiteScore

6.40

自引率

5.00%

发文量

194

审稿时长

3-8 weeks

期刊介绍： The Bulletin of the Chemical Society of Japan (BCSJ) is devoted to the publication of scientific research papers in the fields of Theoretical and Physical Chemistry, Analytical and Inorganic Chemistry, Organic and Biological Chemistry, and Applied and Materials Chemistry. BCSJ appears as a monthly journal online and in advance with three kinds of papers (Accounts, Articles, and Short Articles) describing original research. The purpose of BCSJ is to select and publish the most important papers with the broadest significance to the chemistry community in general. The Chemical Society of Japan hopes all visitors will notice the usefulness of our journal and the abundance of topics, and welcomes more submissions from scientists all over the world.