取代基对有效形成氢键胶囊的相互诱导配合过程的影响

IF 16.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Accounts of Chemical Research Pub Date : 2024-08-06 DOI:10.1002/jccs.202400140

Sarvjeet Kaur, M. M. Lee, Shih-Sheng Sun, Ashutosh S. Singh

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引用次数: 0

摘要

由于分子成分之间存在强烈的π---π相互作用，由π共轭成分形成的分子空穴一般会在没有客体分子的情况下趋于塌陷，尤其是在溶液状态下。最近，我们探讨了相互诱导拟合效应对解决这一问题的重要性。在本报告中，我们展示了人工体系中取代基对相互诱导拟合过程有效性的作用。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Effect of substituents on mutual induced-fit process, responsible for effective hydrogen-bonded capsule formation

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Effect of substituents on mutual induced-fit process, responsible for effective hydrogen-bonded capsule formation

Molecular cavities formed by π-conjugated component(s) generally, tend to collapse in the absence of guest molecule(s) especially in the solution-state, because of strong π•••π interactions between molecular components. Recently, we have explored the importance of mutual induced-fit effect to sort out this issue. In the present report, we have shown the role of substituents on the effectiveness of mutual induced-fit process in an artificial system.

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来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

期刊介绍： Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.