{"title":"利用过硫酸盐介导的封闭 Fe0 催化剂进行磺胺甲噁唑降解的超快 Fenton 类反应","authors":"Chundi Zhou, Yali Guo, Songhang Du, Minghao Sui","doi":"10.1016/j.apcatb.2024.124442","DOIUrl":null,"url":null,"abstract":"Herein, a nanoconfinement strategy was employed to encapsulate nano zero-valent iron (confined-Fe) for the rapid degradation of sulfamethoxazole (SMX) through a peroxymonosulfate (PMS)-mediated Fenton-like reaction. The confined-Fe catalyst was synthesized in situ using a liquid-phase reduction method, incorporating nitrilotriacetic acid (NA) modified carboxylated carbon nanotube (FOC-N-6). Comprehensive experimental analyses and characterizations demonstrated the FOC-N-6 catalyst facilitated rapid electron transfer through the carbon framework and the surface PMS reactive complex (FOC-N-6-PMS*). This process accelerated the Fe(III)/Fe(II) redox cycle and promoted the formation of surface Fe(II) active sites (Fe-OCNT-COOFe(II)-), which served as dominant adsorption sites for PMS. Density functional theory (DFT) calculations revealed that the confined-Fe structure can decrease the adsorption energy () of PMS on the FOC-N-6 surface. And the FOC-N-6-PMS* facilitated the rapid degradation of SMX through both non-radical and radical pathways. This confined-Fe catalytic strategy holds promise as a viable method for controlling emerging contaminants.","PeriodicalId":516528,"journal":{"name":"Applied Catalysis B: Environment and Energy","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2024-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Ultrafast Fenton-like reaction using a peroxymonosulfate-mediated confined-Fe0 catalyst for the degradation of sulfamethoxazole\",\"authors\":\"Chundi Zhou, Yali Guo, Songhang Du, Minghao Sui\",\"doi\":\"10.1016/j.apcatb.2024.124442\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Herein, a nanoconfinement strategy was employed to encapsulate nano zero-valent iron (confined-Fe) for the rapid degradation of sulfamethoxazole (SMX) through a peroxymonosulfate (PMS)-mediated Fenton-like reaction. The confined-Fe catalyst was synthesized in situ using a liquid-phase reduction method, incorporating nitrilotriacetic acid (NA) modified carboxylated carbon nanotube (FOC-N-6). Comprehensive experimental analyses and characterizations demonstrated the FOC-N-6 catalyst facilitated rapid electron transfer through the carbon framework and the surface PMS reactive complex (FOC-N-6-PMS*). This process accelerated the Fe(III)/Fe(II) redox cycle and promoted the formation of surface Fe(II) active sites (Fe-OCNT-COOFe(II)-), which served as dominant adsorption sites for PMS. Density functional theory (DFT) calculations revealed that the confined-Fe structure can decrease the adsorption energy () of PMS on the FOC-N-6 surface. And the FOC-N-6-PMS* facilitated the rapid degradation of SMX through both non-radical and radical pathways. This confined-Fe catalytic strategy holds promise as a viable method for controlling emerging contaminants.\",\"PeriodicalId\":516528,\"journal\":{\"name\":\"Applied Catalysis B: Environment and Energy\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-07-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Catalysis B: Environment and Energy\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1016/j.apcatb.2024.124442\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Catalysis B: Environment and Energy","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1016/j.apcatb.2024.124442","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Ultrafast Fenton-like reaction using a peroxymonosulfate-mediated confined-Fe0 catalyst for the degradation of sulfamethoxazole
Herein, a nanoconfinement strategy was employed to encapsulate nano zero-valent iron (confined-Fe) for the rapid degradation of sulfamethoxazole (SMX) through a peroxymonosulfate (PMS)-mediated Fenton-like reaction. The confined-Fe catalyst was synthesized in situ using a liquid-phase reduction method, incorporating nitrilotriacetic acid (NA) modified carboxylated carbon nanotube (FOC-N-6). Comprehensive experimental analyses and characterizations demonstrated the FOC-N-6 catalyst facilitated rapid electron transfer through the carbon framework and the surface PMS reactive complex (FOC-N-6-PMS*). This process accelerated the Fe(III)/Fe(II) redox cycle and promoted the formation of surface Fe(II) active sites (Fe-OCNT-COOFe(II)-), which served as dominant adsorption sites for PMS. Density functional theory (DFT) calculations revealed that the confined-Fe structure can decrease the adsorption energy () of PMS on the FOC-N-6 surface. And the FOC-N-6-PMS* facilitated the rapid degradation of SMX through both non-radical and radical pathways. This confined-Fe catalytic strategy holds promise as a viable method for controlling emerging contaminants.