准一维约束下活性物质体系的汽液转变动力学

Parameshwaran A, Bhaskar Sen Gupta
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引用次数: 0

摘要

我们利用分子动力学模拟研究了四维封闭活性物质体系中的汽液相分离动力学。活性是通过维克塞克(Vicsek)规则激发的,而被动相互作用则遵循伦纳德-琼斯(Lennard-Jones)势能。当系统密度接近蒸气支时,演化形态以断开的液体簇为特征。在被动极限下,粗化始于成核,然后是蒸发-冷凝生长机制,最终导致没有完全相分离的蜕变状态。我们的目的是了解类似维克塞克的自推进对这些团簇的结构和生长的影响。我们的主要发现是,Vicsek 活动导致了一种独特的生长机制,特别是快速的团簇生长和通过弹道聚集打破了逸散状态。我们利用适当的理论模型分析和解释了相关的生长规律。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Kinetics of vapor-liquid transition of active matter system under quasi one-dimensional confinement
We study the kinetics of vapor-liquid phase separation in a quasi one-dimensional confined active matter system using molecular dynamics simulations. Activity is invoked via the Vicsek rule, while passive interaction follows the Lennard-Jones potential. With the system density near the vapor branch, the evolution morphology features disconnected liquid clusters. In the passive limit, coarsening begins with nucleation, followed by an evaporation-condensation growth mechanism, leading to a metastable state without complete phase separation. We aim to understand the impact of Vicsek-like self-propulsion on the structure and growth of these clusters. Our key finding is that Vicsek activity results in a distinct growth mechanism, notably rapid cluster growth and the breakdown of the metastable state through ballistic aggregation. Relevant growth laws are analyzed and explained using appropriate theoretical models.
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