塞尔维亚缺氧冲积含水层铵来源的综合分析:物理化学、同位素和微生物学数据的启示

IF 3.1 3区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS
Marija Perović , Vesna Obradović , Vesna Zuber-Radenković , David Mitrinović , Kay Knoeller , Maja Turk Sekulić
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引用次数: 0

摘要

75% 的欧盟人口依靠地下水供水,这凸显了检查地下水质量的重要性。在塞尔维亚共和国,50% 以上用于公共供水的地下水来自冲积含水层,其中 80-90% 的水源来自河水渗透。本研究调查了塞尔维亚 Kovin-Dubovac 地区附近多瑙河冲积含水层中铵浓度增加(最高达 4.7 mgN/l)的原因,该地区是未来潜在的区域供水水源地,周围有密集的农业生产和露天煤矿。综合研究包括对物理化学数据(33 个采样点的 13 个参数)、同位素分析(12 个样本中的δN-NH;5 个样本中的δS-SO、δO-SO)和微生物测试(15 个样本中的反硝化菌、硫酸盐还原菌、铁相关菌和异养需氧菌)进行统计处理。因子分析显示,自生有机物来源指标(铁、铁和总有机碳)、地质基质成分(Na、HS、Cl)和地下水状态参数(pH、Eh 和 NH)之间存在明显的正负载(大于 0.5)。这种多方面的方法以及提取的主成分中相关参数的空间浓度梯度揭示了两种 NH 来源的主导地位。河岸地带的特点是沉积物有机物矿化、铁含量增加和天然铵来源(δN-NH 从 +4.82‰ 到 +6.93‰),同时还具有适合 DNRA 和硫酸盐还原的条件。接近腹地时,铁和总有机物含量降低,氧化还原值增加,显示出施肥的特征(δN-NH -0.84‰和-0.33‰),这与反硝化作用的影响有关。这种多层面的方法减少了模糊性,在辨别氮的来源和含水层在地下水减少环境中氮流失或保存的潜力时,可对结果做出更清晰的解释。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Integrated analysis of ammonium origins in a Serbian anoxic alluvial aquifer: Insight from physicochemical, isotopic, microbiological data

The significance of examining groundwater quality is highlighted by the fact that 75% of the European Union population relies on groundwater for their water supply. In the Republic of Serbia, over 50% of the groundwater used for public water supply comes from alluvial aquifers, with 80–90% of this water originating from river water infiltration. This study investigates the origin of increased ammonium concentrations (up to 4.7 mgN/l) in the Danube alluvial aquifer near Kovin-Dubovac area, Serbia, a potential future regional water supply source surrounded by intensive agricultural production and an open coal mine. Comprehensive research involved statistical processing of physicochemical data (13 parameters from 33 sampling sites), isotopic analyses (δ15N–NH4 – 12 samples; δ34S–SO4, δ18O–SO4 in 5 samples), and microbiological tests (denitrifying, sulphate-reducing, iron-related, and heterotrophic aerobic bacteria in 15 samples). Factor analysis revealed significant positive loadings (>0.5) among indicators of autochthonous organic matter origin (Fe2+, Fetot, and TOC), geological matrix components (Na, H2S, Cl), and groundwater state parameters (pH, Eh, and NH4+). This multifaceted approach and the spatial concentration gradients of parameters associated within extracted principal components revealed the predominance of two NH4+ sources. The riparian zone is characterized by sediment organic matter mineralization, increased iron content, and natural ammonium origin (δ15N–NH4+ from +4.82‰ to +6.93‰) accompanied by conditions suitable for DNRA and sulphate reduction. Approaching to the hinterland lower iron and total organic matter content, accompanied by increased redox values revealed the signature of fertilizers application (δ15N–NH4+ −0.84‰ and −0.33‰), associated with denitrification influence. This multifaceted approach reduces ambiguity, providing a clearer interpretation of results when discerning the origin of nitrogen and aquifer potential for nitrogen loss or conservation in a reducing groundwater environment.

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来源期刊
Applied Geochemistry
Applied Geochemistry 地学-地球化学与地球物理
CiteScore
6.10
自引率
8.80%
发文量
272
审稿时长
65 days
期刊介绍: Applied Geochemistry is an international journal devoted to publication of original research papers, rapid research communications and selected review papers in geochemistry and urban geochemistry which have some practical application to an aspect of human endeavour, such as the preservation of the environment, health, waste disposal and the search for resources. Papers on applications of inorganic, organic and isotope geochemistry and geochemical processes are therefore welcome provided they meet the main criterion. Spatial and temporal monitoring case studies are only of interest to our international readership if they present new ideas of broad application. Topics covered include: (1) Environmental geochemistry (including natural and anthropogenic aspects, and protection and remediation strategies); (2) Hydrogeochemistry (surface and groundwater); (3) Medical (urban) geochemistry; (4) The search for energy resources (in particular unconventional oil and gas or emerging metal resources); (5) Energy exploitation (in particular geothermal energy and CCS); (6) Upgrading of energy and mineral resources where there is a direct geochemical application; and (7) Waste disposal, including nuclear waste disposal.
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