过渡金属促进的可转换级联过程：通过远程三氟甲基氮化/1、正酰基迁移序列合成多种含 N 化合物

IF 4.7 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Chemistry Frontiers Pub Date : 2024-08-07 DOI:10.1039/D4QO00934G

Ji-Ming Xi, Yan-Xin Zhang, Zhong-Lin Wei and Wei-Wei Liao

引用次数: 0

摘要

在此，我们介绍了一种过渡金属促进的可切换级联转化方法，通过远程三氟甲基偶氮化/1、n-酰基迁移序列制备功能化氨基吡咯啉和双环三嗪-x(yH)-酮衍生物，其中使用了可用的 N-氰化物、TMSN3 和 Togni 试剂。此外，还证明了相应的重氮化变体。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Transition metal-promoted switchable cascade processes: diverse synthesis of N-containing compounds through a remote trifluoromethylazidation/1,n-acyl migration sequence†

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Transition metal-promoted switchable cascade processes: diverse synthesis of N-containing compounds through a remote trifluoromethylazidation/1,n-acyl migration sequence†

Here, we described a transition metal-promoted switchable cascade transformation for the preparation of functionalized aminopyrroline and bicyclic triazin-x(yH)-one derivatives via a remote trifluoromethylazidation/1,n-acyl migration sequence, in which available N-cyanamides, TMSN₃ and Togni reagent were employed. In addition, the corresponding diazidation variant has also been demonstrated.

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来源期刊

Organic Chemistry Frontiers CHEMISTRY, ORGANIC-

CiteScore

7.90

自引率

11.10%

发文量

686

审稿时长

1 months

期刊介绍： Organic Chemistry Frontiers is an esteemed journal that publishes high-quality research across the field of organic chemistry. It places a significant emphasis on studies that contribute substantially to the field by introducing new or significantly improved protocols and methodologies. The journal covers a wide array of topics which include, but are not limited to, organic synthesis, the development of synthetic methodologies, catalysis, natural products, functional organic materials, supramolecular and macromolecular chemistry, as well as physical and computational organic chemistry.