对慢速 He$^{2+}$ 和 He$^{+}$-Ne$_2$ 碰撞中电子去除过程的研究表明原子间库仑衰变产率很高

Darij Starko, Tom Kirchner
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引用次数: 0

摘要

我们采用独立原子和独立电子模型来研究 He$^{2+}$ 和 He$^{+}$ 离子射弹在氖二聚物靶上的碰撞系统。二聚体被设定为静止在其平衡键长上,射弹以与碰撞能量 10 keV/amu 相对应的速度平行于二聚体轴移动。对这些碰撞的分析采用了称为多项式和行列式的两种方法。每种分析都分为不包含和包含由于二聚体的电子俘获而导致的射弹电荷状态变化的两类模型。所有计算均使用冷冻原子靶和动态响应模型,并使用耦合通道双中心基发生器方法进行轨道传播。我们计算了所有的单电子和双电子剔除过程,但特别关注了那些由于与原子间库仑衰变(ICD)相关联而导致 Ne$^{+}$-Ne$^{+}$ 碎片通道的剔除过程。我们在所有的分析和模型中都证实,Ne(2$s$)的电子去除能力很强,因此 ICD 将有助于二聚体的碎裂,这一点在之前已经得到了证实。考虑到射弹电荷状态变化的模型表明,当使用 He$^{+}$ 射弹时,会产生纯粹的 ICD 产物。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Investigations of electron removal processes in slow He$^{2+}$ and He$^{+}$-Ne$_2$ collisions indicate high Interatomic Coulombic Decay yield
We implement an independent-atom and independent-electron model to investigate the collision systems of He$^{2+}$ and He$^{+}$ ion projectiles impinging on a neon dimer target. The dimer is set to be stationary at its equilibrium bond length with the projectile traveling parallel to the dimer axis at a speed corresponding to the collision energy of 10 keV/amu. Two approaches called multinomial and determinantal are used as an analysis of these collisions. Each of the analyses is broken down into two types of models that do not and do include a change in the projectile charge state due to electron capture from the dimer. All calculations are performed using both a frozen atomic target and a dynamic response model using the coupled-channel two-center basis generator method for orbital propagation. All one- and two- electron removal processes are calculated, though particular attention is paid to those that result in the Ne$^{+}$-Ne$^{+}$ fragmentation channel due to its association with interatomic Coulombic decay (ICD). We confirm in all analyses and models that Ne(2$s$) electron removal is strong so that ICD will contribute to dimer fragmentation as has been previously demonstrated. The model that takes into account the change in projectile charge state indicates that there is a pure ICD yield when utilizing a He$^{+}$ projectile.
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