{"title":"催化纳米粒子存在时甲烷激光热化学相关非稳态问题的数学建模","authors":"E. E. Peskova","doi":"10.1134/S1064562424702107","DOIUrl":null,"url":null,"abstract":"<p>A finite-volume algorithm with splitting over physical processes is developed to model nonstationary problems of laser thermochemistry with catalytic nanoparticles in subsonic gas flows. Two-phase flows in a heated pipe with laser radiation and radical kinetics of nonoxidative methane conversion are simulated. It is shown that the conversion of methane at the outlet of the pipe is more than 60% with predominant formation of ethylene and hydrogen.</p>","PeriodicalId":0,"journal":{"name":"","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Mathematical Modeling of Nonstationary Problems Related to Laser Thermochemistry of Methane in the Presence of Catalytic Nanoparticles\",\"authors\":\"E. E. Peskova\",\"doi\":\"10.1134/S1064562424702107\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>A finite-volume algorithm with splitting over physical processes is developed to model nonstationary problems of laser thermochemistry with catalytic nanoparticles in subsonic gas flows. Two-phase flows in a heated pipe with laser radiation and radical kinetics of nonoxidative methane conversion are simulated. It is shown that the conversion of methane at the outlet of the pipe is more than 60% with predominant formation of ethylene and hydrogen.</p>\",\"PeriodicalId\":0,\"journal\":{\"name\":\"\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0,\"publicationDate\":\"2024-07-31\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"\",\"FirstCategoryId\":\"100\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1064562424702107\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"","FirstCategoryId":"100","ListUrlMain":"https://link.springer.com/article/10.1134/S1064562424702107","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Mathematical Modeling of Nonstationary Problems Related to Laser Thermochemistry of Methane in the Presence of Catalytic Nanoparticles
A finite-volume algorithm with splitting over physical processes is developed to model nonstationary problems of laser thermochemistry with catalytic nanoparticles in subsonic gas flows. Two-phase flows in a heated pipe with laser radiation and radical kinetics of nonoxidative methane conversion are simulated. It is shown that the conversion of methane at the outlet of the pipe is more than 60% with predominant formation of ethylene and hydrogen.