碳酸盐化合物与钠离子和钾离子相互作用的 SIT 模型参数说明了关联性

IF 3.1 3区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS
Andrey V. Plyasunov, Elena V. Cherkasova
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引用次数: 0

摘要

目前的研究致力于确定在 298.15 K 下 CO2(aq)、HCO3- 和 CO32- 与 Na+ 和 K+ 离子相互作用的 SIT 系数。SIT 模型是一个简单但物理上合理的水溶液活性系数模型,每个阳离子-阴离子或溶解气体-电解质相互作用只有一个参数。在碳酸盐体系中遇到的问题包括碳酸盐溶液中的水解和歧化副反应,这使得数据分析变得复杂,并导致不同权威实验室测定的活度系数值差异异常大,最高可达 9%。对于 Na2CO3 和 K2CO3 溶液,有必要考虑离子对 M++CO32-=MCO3- 的形成反应,对于 M+=Na+,平衡常数 β1o 等于 log10β1o= 0.75 ± 0.08;对于 M+=K+,平衡常数 β1o 等于 log10β1o= 0.67 ± 0.11。总共有 20 多个二元 SIT 相互作用系数的值。所有结果均在 298.15 K、0.1 MPa 条件下有效。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The SIT model parameters for interactions of carbonate compounds with sodium and potassium ions accounting for association

The current study is devoted to the determination of the SIT coefficients at 298.15 K for interactions, involving CO2(aq), HCO3, and CO32, with mostly Na+ and K+ ions. The SIT model is a simple yet physically sound model for activity coefficients in aqueous solutions, that has just one parameter for each cation-anion or a dissolved gas – electrolyte interaction. Among the issues that were met for carbonate systems are the side reactions of hydrolysis and disproportionation in the carbonate solutions, that complicate the analysis of data and lead to unusually large difference, up to 9%, in the values of activity coefficients, determined in different authoritative laboratories. For Na2CO3 and K2CO3 solutions, it was necessary to take into account the reaction of formation of the ionic pair M++CO32=MCO3, with the equilibrium constants β1o equal to log10β1o= 0.75 ± 0.08 for M+=Na+ and to log10β1o= 0.67 ± 0.11 for M+=K+. In all, there are values for more than 20 binary SIT interaction coefficients. All results are valid at 298.15 K, 0.1 MPa.

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来源期刊
Applied Geochemistry
Applied Geochemistry 地学-地球化学与地球物理
CiteScore
6.10
自引率
8.80%
发文量
272
审稿时长
65 days
期刊介绍: Applied Geochemistry is an international journal devoted to publication of original research papers, rapid research communications and selected review papers in geochemistry and urban geochemistry which have some practical application to an aspect of human endeavour, such as the preservation of the environment, health, waste disposal and the search for resources. Papers on applications of inorganic, organic and isotope geochemistry and geochemical processes are therefore welcome provided they meet the main criterion. Spatial and temporal monitoring case studies are only of interest to our international readership if they present new ideas of broad application. Topics covered include: (1) Environmental geochemistry (including natural and anthropogenic aspects, and protection and remediation strategies); (2) Hydrogeochemistry (surface and groundwater); (3) Medical (urban) geochemistry; (4) The search for energy resources (in particular unconventional oil and gas or emerging metal resources); (5) Energy exploitation (in particular geothermal energy and CCS); (6) Upgrading of energy and mineral resources where there is a direct geochemical application; and (7) Waste disposal, including nuclear waste disposal.
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