{"title":"双组分和三组分系统中氯化盐水的密度建模","authors":"Andrés Soto-Bubert , Joaquin Miranda , Rashmi Bhardwaj , Satheeshkumar Rajendran , Roberto Acevedo","doi":"10.1016/j.ctta.2024.100137","DOIUrl":null,"url":null,"abstract":"<div><p>The paper presents a semi-empirical approach to determining densities of chlorinated brines in the 0–4 molal concentration range and 293.15–323.15 K temperature range. This model incorporates continuous density functions for chlorinated salts and temperature, offering enhanced accuracy and reduced errors in density estimations for complex brine systems, including ternary systems. The model provides precise density estimations for applications like seawater and salt flats by considering ion activities and specific concentration ranges. Comparative analysis shows the model's superior performance with error adjustments consistently below 0.2 %. The continuous variable temperature model proves more effective than discrete approaches, contributing to more accurate density predictions.</p></div>","PeriodicalId":9781,"journal":{"name":"Chemical Thermodynamics and Thermal Analysis","volume":"15 ","pages":"Article 100137"},"PeriodicalIF":0.0000,"publicationDate":"2024-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2667312624000105/pdfft?md5=311715668d7c28afaa7863246e720d80&pid=1-s2.0-S2667312624000105-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Density modeling of chlorinated brines in two and three-component systems\",\"authors\":\"Andrés Soto-Bubert , Joaquin Miranda , Rashmi Bhardwaj , Satheeshkumar Rajendran , Roberto Acevedo\",\"doi\":\"10.1016/j.ctta.2024.100137\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The paper presents a semi-empirical approach to determining densities of chlorinated brines in the 0–4 molal concentration range and 293.15–323.15 K temperature range. This model incorporates continuous density functions for chlorinated salts and temperature, offering enhanced accuracy and reduced errors in density estimations for complex brine systems, including ternary systems. The model provides precise density estimations for applications like seawater and salt flats by considering ion activities and specific concentration ranges. Comparative analysis shows the model's superior performance with error adjustments consistently below 0.2 %. The continuous variable temperature model proves more effective than discrete approaches, contributing to more accurate density predictions.</p></div>\",\"PeriodicalId\":9781,\"journal\":{\"name\":\"Chemical Thermodynamics and Thermal Analysis\",\"volume\":\"15 \",\"pages\":\"Article 100137\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-07-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2667312624000105/pdfft?md5=311715668d7c28afaa7863246e720d80&pid=1-s2.0-S2667312624000105-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Thermodynamics and Thermal Analysis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2667312624000105\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Thermodynamics and Thermal Analysis","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2667312624000105","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
本文介绍了一种半经验方法,用于确定 0-4 摩尔浓度范围和 293.15-323.15 K 温度范围内氯化盐水的密度。该模型结合了氯化盐和温度的连续密度函数,提高了复杂盐水系统(包括三元系统)密度估算的准确性并减少了误差。通过考虑离子活性和特定浓度范围,该模型可为海水和盐滩等应用提供精确的密度估算。对比分析表明,该模型性能优越,误差调整始终低于 0.2%。事实证明,连续变温模型比离散方法更有效,有助于进行更精确的密度预测。
Density modeling of chlorinated brines in two and three-component systems
The paper presents a semi-empirical approach to determining densities of chlorinated brines in the 0–4 molal concentration range and 293.15–323.15 K temperature range. This model incorporates continuous density functions for chlorinated salts and temperature, offering enhanced accuracy and reduced errors in density estimations for complex brine systems, including ternary systems. The model provides precise density estimations for applications like seawater and salt flats by considering ion activities and specific concentration ranges. Comparative analysis shows the model's superior performance with error adjustments consistently below 0.2 %. The continuous variable temperature model proves more effective than discrete approaches, contributing to more accurate density predictions.