Flux enhancement with titanium or vanadium oxides addition for superior submerged arc welding of HSLA steel plates

A high-strength low-alloy (HSLA) steel plate of 10 mm thickness underwent submerged arc welding with enhanced fluxes containing additional titanium oxide (TiO₂) or vanadium oxide (V₂O₅). The addition of TiO₂ led to the development of a finer acicular ferrite structure but coarsening the carbide and martensite/austenite (M/A) constituents, which marginally improved the hardness, tensile strength, and ductility of weld metal. Conversely, incorporating V₂O₅ facilitated a substantial vanadium absorption (0.7 wt. %) in the weld metal, giving rise to a distinctive acicular microstructure less reliant on ferrite nucleation at non-metallic inclusions than conventional acicular ferrite. The distinctive microstructure, unique to vanadium steels, combined lath bainite with irregularly shaped granular bainite. The resultant dual-mode bainitic structure, coupled with a more uniform distribution of refined microphase constituents, outperformed the conventional acicular ferrite, delivering more than 20% and 13% improvements in yield and tensile strengths respectively, as evidenced by transverse tensile tests on the weld metals.