麻风树籽油非三酸甘油酯成分的鉴定

Fai F. Yirankinyunki, H. M. Adamu, Auwal A. Muhammad, Muhammad A. Shibdawa
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引用次数: 0

摘要

植物油主要是由饱和和不饱和脂肪酸组成的甘油三酯,但也含有少量非甘油三酯成分,这些成分属于不同的化学类别,可能会影响植物油的营养价值或抗营养价值。麻疯树油不可食用,因为它被认为含有麻疯树种子中的一种毒素和肿瘤促进剂--磷脂。这项研究旨在确定麻疯树油挥发性成分的含量。麻疯树种子用正己烷以索氏提取法提取,并测定了碘值、酸值和过氧化值等质量参数。傅立叶变换红外光谱法(FTIR)和气相色谱-质谱法(GC-MS)分析是为了确定油中的挥发性化合物。出油率为 43.17%,碘值、酸值和过氧化值分别为 100 mgI2 /100 g、2.39 mgKOH/g 和 8.36 meq/kg。傅立叶变换红外光谱分析显示,其中的化合物具有烷、烯、醇、酯羧酸、胺和羰基等官能团。气相色谱-质谱分析显示存在 20 种不同化学类别的化合物。结论是麻风树籽油中除了甘油三酯外,还含有多种不同类型的化合物。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Identification of the constituent of non-triglyceride components of Jatropha seed oil
Vegetable oils are mostly triglyceride of saturated and unsaturated fatty acid, but they also contain a small percentage of non- triglyceride components that belong to wide chemical classes and could contribute to the nutritive value or anti-nutritional value of the vegetable oil. Jatropha oil is non edible because it is considered to contain phorbol ester, a toxin and a tumour promoter that is found in jatropha seeds. This research was carried out with the aim of identifying the content of the volatile component of jatropha oil. Jatropha seeds were extracted with n-hexane using soxhlet extraction method and quality parameters of iodine value, acid value and peroxide value were determined. The Fourier Transform-Infrared spectroscopy (FTIR) and Gas Chromatography-Mass Spectrometry (GC-MS) analysis were carried out in order to identify the volatile chemical compounds in the oil. The oil yield was 43.17%, and the iodine value, acid value and peroxide values were 100 mgI2 /100 g, 2.39 mgKOH/g, and 8.36 meq/kg respectively. The FT-IR analysis revealed the presence of compounds with the functional groups of alkanes, alkenes, alcohols, esters carboxylic acid, amine and carbonyl. The GC-MS analysis showed the presence of twenty compounds of different chemical classes. It was concluded that jatropha seed oil contains many different types of compounds in addition to triglycerides.
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