制备用于光催化降解亚甲基蓝的掺锰氧化铋

Mansoor Jamal, Gul Asimullah Khan, Hao Sun, Khair Ullah, Osama Ali Khattak, Muhammad Kashif, Salman Khan, Mohsin Alam, Shah Hussain, Mati Ullah, Seeqal Aleena, Hameedul Haq, Saira Umar, Muhammad Atif, Ijaz Hussain, Aalia Masood
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引用次数: 0

摘要

本研究介绍了一种利用掺杂锰的 Bi2O3 纳米粒子(NPs)在紫外线照射下降解亚甲基蓝染料的独特方法。掺杂锰的 Bi2O3 纳米粒子(NPs)是通过水热法生产的。扫描电子显微镜 (SEM)、能量色散 X 射线分析 (EDX)、傅立叶变换红外光谱 (FTIR)、X 射线衍射 (XRD) 等被用来表征制备的纳米粒子。研究发现,Mn/ Bi2O3 NPs 的带隙分别为 2%、3% 和 4%,为 4.13 eV、3.92 eV 和 3.77 eV。利用傅立叶变换红外光谱(FT-IR)鉴定官能团。掺锰的 Bi2O3 纳米粒子在不同放大倍率下被扫描电镜拍摄,照片清晰地显示了粒子的立方体和圆柱形双重形态。XRD 数据显示,掺锰的 Bi2O3 颗粒呈结晶状,平均直径为 20 纳米。在染料浓度分别为 2%、3% 和 4% 的实验条件下,Mn/Bi2O3 在 150 分钟时间间隔内的光降解效率分别为 90.29%、91.6% 和 93.16%。在理想的催化剂用量为 0.2 克、浓度为 40 ppm 时,可以观察到很高的染料降解率。锌氧化物中已经掺入了多种金属,但还没有关于 Bi2O3 掺入锰的研究。此外,还首次利用它来研究亚甲基蓝染料的劣化。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Preparation of Manganese Doped Bismuth Oxide for the photocatalytic Degradation of Methylene Blue
The current study describes a unique method for degrading methylene blue dye utilizing Mn-doped Bi2O3 nanoparticles (NPs) exposed to UV light. Bi2O3 nanoparticles (NPs) doped with Mn were produced using a hydrothermal process. Scanning electron microscopy (SEM), energy-dispersive X-ray analysis (EDX), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and were use to characterize the prepared nanoparticles. It was discovered that the band gaps of Mn/ Bi2O3 NPs are 2%, 3%, and 4%, respectively, and are 4.13 eV, 3.92 eV, and 3.77 eV. Functional group identification using Fourier transforms infrared spectroscopy (FT-IR). Mn-doped Bi2O3 nanoparticles were captured in SEM pictures at various magnifications, and the photos clearly display the particles' dual morphologies, cubic and cylindrical. The Mn-doped Bi2O3 particles were found to be crystalline, with mean diameters of 20 nm, according to the XRD data. The photodegradation efficiency of Mn/Bi2O3 at experimental dye concentrations of 2%, 3%, and 4% was determined to be 90.29, 91.6, and 93.16 percent, respectively, over a 150 minute time interval. At the ideal catalyst dosage of 0.2 g and concentration of 40 ppm, a high percentage of dye degradation was observed. Numerous metals have been doped into zinc oxides, although no work has documented doping of Bi2O3 with Mn. Additionally, it was utilized for the first time to look at the deterioration of Methylene Blue dye.
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