将铜集流器的 3D 打印与结构性锂离子电池电极材料的电泳沉积相结合

IF 4.2 2区 工程技术 Q2 ENGINEERING, MANUFACTURING
Ana C. Martinez, Alexis Maurel, Bharat Yelamanchi, A. Alec Talin, Sylvie Grugeon, Stéphane Panier, Loic Dupont, Ana Aranzola, Eva Schiaffino, Sreeprasad T. Sreenivasan, Pedro Cortes, Eric MacDonald
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引用次数: 0

摘要

作为概念验证,这项研究利用增材制造和电泳沉积技术实现了具有承重和储能双重功能的结构性锂离子电池。本文介绍了复杂的三维打印铜集流器的制备步骤,包括光固化树脂配方的配制、大桶光聚合工艺,以及基于前驱体的溶液浸泡步骤和热后处理。结果表明,3D 打印铜集流器的压缩和微硬度测试表明其具有足够的机械性能。然后在三维打印的铜集电体上电泳沉积了石墨作为负极活性材料和其他添加剂,目的是展示其储能功能。三维多材料集流器/负电极与锂金属的半电池电化学循环最终表明,通过这种方法可以成功获得结构电池组件。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Combining 3D printing of copper current collectors and electrophoretic deposition of electrode materials for structural lithium-ion batteries

Combining 3D printing of copper current collectors and electrophoretic deposition of electrode materials for structural lithium-ion batteries

Serving as a proof of concept, additive manufacturing and electrophoretic deposition are leveraged in this work to enable structural lithium-ion batteries with load-bearing and energy storage dual functionality. The preparation steps of a complex 3D printed copper current collector, involving the formulation of a photocurable resin formulation, as well as the vat photopolymerization process followed by a precursors-based solution soaking step and thermal post-processing are presented. Compression and microhardness testing onto the resulting 3D printed copper current collector are shown to demonstrate adequate mechanical performance. Electrophoretic deposition of graphite as a negative electrode active material and other additives was then performed onto the 3D printed copper collector, with the intention to demonstrate energy storage functionality. Half-cell electrochemical cycling of the 3D multi-material current collector/negative electrode versus lithium metal finally demonstrates that structural battery components can be successfully obtained through this approach.

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来源期刊
Advances in Manufacturing
Advances in Manufacturing Materials Science-Polymers and Plastics
CiteScore
9.10
自引率
3.80%
发文量
274
期刊介绍: As an innovative, fundamental and scientific journal, Advances in Manufacturing aims to describe the latest regional and global research results and forefront developments in advanced manufacturing field. As such, it serves as an international platform for academic exchange between experts, scholars and researchers in this field. All articles in Advances in Manufacturing are peer reviewed. Respected scholars from the fields of advanced manufacturing fields will be invited to write some comments. We also encourage and give priority to research papers that have made major breakthroughs or innovations in the fundamental theory. The targeted fields include: manufacturing automation, mechatronics and robotics, precision manufacturing and control, micro-nano-manufacturing, green manufacturing, design in manufacturing, metallic and nonmetallic materials in manufacturing, metallurgical process, etc. The forms of articles include (but not limited to): academic articles, research reports, and general reviews.
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