稀释甲烷-氧气混合物燃烧前沿与中空圆柱形和锥形障碍物在低压下的相互作用特征

IF 1.4 4区 化学 Q4 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL
K. Ya. Troshin, N. M. Rubtsov, V. I. Chernysh, G. I. Tsvetkov
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引用次数: 0

摘要

摘要 研究表明,在 298 K 和 100-300 Torr 条件下,充分混合的稀甲烷-氧气混合物的火焰前端在向空心圆柱形和圆锥形障碍物的两端传播时,不会在障碍物后面形成冯-卡尔曼路径(涡流脱落);然而,在障碍物后的热产物流中,在相同条件下会出现这种不稳定性。在火焰传播过程中,在障碍物后面观察不到涡流脱落,但在热产品反射流的传播过程中却出现了涡流脱落,其原因是导热性降低了火焰的曲率,导致火焰趋于稳定。事实上,在可燃混合物中,化学反应区的凸面区域比平面火焰中的冷面区域释放出更多的热量:凸面区域的热量不仅沿火焰传播方向向前传递,而且还向横向传递。由此产生的反应区冷却导致向前喷发的火焰区域落后。在凹面区域观察到的情况恰恰相反,这里的温度上升也是出于同样的原因。反应速度加快,随着火焰的扩散,反应速度也加快。因此,火焰弯曲前端的表面变得均匀。换句话说,导热性对弯曲火焰具有稳定作用。而在非反应性气体中则没有这种效果。在非反应气体中没有这种效果。根据可压缩反应介质的 Navier-Stokes 方程的声学近似计算,可以考虑到所观察到的火焰前沿接近圆柱形障碍物时的主要特征:在火焰传播过程中,在障碍物后面观察不到涡流脱落。因此,通过定性模型可以获得化学惰性气体中冯-卡尔曼不稳定性的出现模式以及火焰传播过程中不存在这种不稳定性的情况。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Features of the Interaction of the Combustion Front of Diluted Methane–Oxygen Mixtures with Hollow Cylindrical and Conical Obstacles at Low Pressures

Features of the Interaction of the Combustion Front of Diluted Methane–Oxygen Mixtures with Hollow Cylindrical and Conical Obstacles at Low Pressures

Abstract

It is shown that the front of the flame of a thoroughly mixed diluted methane-oxygen mixture at 298 K and 100–300 Torr propagating to the ends of hollow cylindrical and conical obstacles does not form a von Kármán path (vortex shedding) behind them; however, this instability occurs under the same conditions in the flow of hot products after obstacles. The reason that vortex shedding is not observed behind an obstacle during flame propagation but appears in the course of propagation of a reflected stream of hot products is that thermal conductivity reduces the curvature of the flame and leads to its stabilization. Indeed, the convex areas of the chemical reaction zone in a combustible mixture give off more heat in relation to cold ones than in a flat flame: the heat from them is not only transmitted forward in the direction of flame propagation but also in the lateral directions. The resulting cooling of the reaction zone causes the flame regions that burst forward to lag behind. The opposite situation is observed in concave areas, where the temperature rises for the same reasons. The rate of reactions increases and they spread forward faster as the flame spreads. Thus, the surface of the curved front of the flame is evened out. In other words, thermal conductivity has a stabilizing effect on a curved flame. This effect is missing in non-reactive gas. This effect is absent in a nonreacting gas. Calculations based on the acoustic approximation of the Navier–Stokes equations for a compressible reacting medium make it possible to take into account the main observed feature of the flame front approaching an obstacle in the form of a cylinder: vortex shedding is not observed behind the obstacle during flame propagation. Thus, a qualitative model allows obtaining both the mode of the emergence of a von Kármán instability in a chemically inert gas and its absence during flame propagation.

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来源期刊
Russian Journal of Physical Chemistry B
Russian Journal of Physical Chemistry B 化学-物理:原子、分子和化学物理
CiteScore
2.20
自引率
71.40%
发文量
106
审稿时长
4-8 weeks
期刊介绍: Russian Journal of Physical Chemistry B: Focus on Physics is a journal that publishes studies in the following areas: elementary physical and chemical processes; structure of chemical compounds, reactivity, effect of external field and environment on chemical transformations; molecular dynamics and molecular organization; dynamics and kinetics of photoand radiation-induced processes; mechanism of chemical reactions in gas and condensed phases and at interfaces; chain and thermal processes of ignition, combustion and detonation in gases, two-phase and condensed systems; shock waves; new physical methods of examining chemical reactions; and biological processes in chemical physics.
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