分子氮在水冷式水慢化能源反应堆主冷却剂辐射分解中的作用

IF 0.9 4区 化学 Q4 CHEMISTRY, PHYSICAL
V. A. Grachev, O. S. Bystrova, A. B. Sazonov
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引用次数: 0

摘要

摘要 介绍了水冷式水慢化能源反应堆(VVER)一次冷却剂中辐射-化学变化的模拟结果。结果表明,在强辐照条件下,溶解在冷却剂中的分子氮具有化学活性。N2 与激发的羟基自由基发生反应,生成氨和亚硝酸。氨的进一步分解只产生氧化形式的氮,而 N2 则是中间产物。只有通过持续添加 NH3 和冷却剂脱气,才能将氨水化学反应中的氢气和氧气浓度保持在正常范围内。相反,在添加 H2 的水化学系统中(在初始阶段),在没有干扰的情况下,很快就能建立一个稳定的系统,满足 VVER 水化学标准的要求。这两种水化学系统之间的差异是由于 NH3 分子中含有氮元素及其作为元素的转化,而与初始化学形态无关。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Role of Molecular Nitrogen in the Radiolysis of the Primary Coolant of a Water-Cooled Water-Moderated Energy Reactor

Role of Molecular Nitrogen in the Radiolysis of the Primary Coolant of a Water-Cooled Water-Moderated Energy Reactor

Abstract

The results of simulation of radiation-chemical transformations in the primary coolant of a water-cooled water-moderated energy reactor (VVER) are presented. It has been shown that under conditions of intense irradiation, molecular nitrogen dissolved in the coolant exhibits chemical activity. The reaction of N2 with the excited hydroxyl radical initiates the formation of ammonia and nitrous acid. Further decomposition of ammonia produces only oxidized forms of nitrogen, with N2 acting as an intermediate product. Maintaining hydrogen and oxygen concentrations within normal limits in the ammonia water chemistry is possible only with constant dosing of NH3 and degassing of the coolant. In the case of water chemistry with H2 dosing (at the initial moment), on the contrary, a stationary regime is quickly established in the absence of disturbances, satisfying the requirements of VVER water chemistry standards. The difference between the two water chemistry systems is due to the presence of nitrogen in the NH3 molecule and its transformations as an element, regardless of the initial chemical form.

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来源期刊
High Energy Chemistry
High Energy Chemistry 化学-物理化学
CiteScore
1.50
自引率
28.60%
发文量
62
审稿时长
6-12 weeks
期刊介绍: High Energy Chemistry publishes original articles, reviews, and short communications on molecular and supramolecular photochemistry, photobiology, radiation chemistry, plasma chemistry, chemistry of nanosized systems, chemistry of new atoms, processes and materials for optical information systems and other areas of high energy chemistry. It publishes theoretical and experimental studies in all areas of high energy chemistry, such as the interaction of high-energy particles with matter, the nature and reactivity of short-lived species induced by the action of particle and electromagnetic radiation or hot atoms on substances in their gaseous and condensed states, and chemical processes initiated in organic and inorganic systems by high-energy radiation.
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