芳香族咪唑存在时多功能(甲基)丙烯酸酯的光聚合动力学

IF 0.9 4区 化学 Q4 CHEMISTRY, PHYSICAL
Yu. E. Begantsova, A. N. Konev
{"title":"芳香族咪唑存在时多功能(甲基)丙烯酸酯的光聚合动力学","authors":"Yu. E. Begantsova, A. N. Konev","doi":"10.1134/s0018143924700231","DOIUrl":null,"url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>The photolysis of a phenanthroline-containing imidazole in a DMSO solution and the initiating ability of the compound in the photopolymerization of multifunctional (meth)acrylates under LED irradiation (λ = 395 nm) in aerobic conditions have been studied for the first time. The relationship between the kinetic parameters of photopolymerization and light intensity and the chemical structure and viscosity of multifunctional monomers has been established.</p>","PeriodicalId":12893,"journal":{"name":"High Energy Chemistry","volume":"27 1","pages":""},"PeriodicalIF":0.9000,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Kinetics of Photopolymerization of Multifunctional (Meth)Acrylates in the Presence of an Aromatic Imidazole\",\"authors\":\"Yu. E. Begantsova, A. N. Konev\",\"doi\":\"10.1134/s0018143924700231\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<h3 data-test=\\\"abstract-sub-heading\\\">Abstract</h3><p>The photolysis of a phenanthroline-containing imidazole in a DMSO solution and the initiating ability of the compound in the photopolymerization of multifunctional (meth)acrylates under LED irradiation (λ = 395 nm) in aerobic conditions have been studied for the first time. The relationship between the kinetic parameters of photopolymerization and light intensity and the chemical structure and viscosity of multifunctional monomers has been established.</p>\",\"PeriodicalId\":12893,\"journal\":{\"name\":\"High Energy Chemistry\",\"volume\":\"27 1\",\"pages\":\"\"},\"PeriodicalIF\":0.9000,\"publicationDate\":\"2024-07-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"High Energy Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1134/s0018143924700231\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"High Energy Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1134/s0018143924700231","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0

摘要

摘要 首次研究了在有氧条件下,LED(λ = 395 nm)照射下,含菲基咪唑在 DMSO 溶液中的光解作用以及该化合物在多功能(甲基)丙烯酸酯光聚合中的引发能力。研究还确定了光聚合动力学参数与光照强度以及多功能单体的化学结构和粘度之间的关系。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Kinetics of Photopolymerization of Multifunctional (Meth)Acrylates in the Presence of an Aromatic Imidazole

Kinetics of Photopolymerization of Multifunctional (Meth)Acrylates in the Presence of an Aromatic Imidazole

Abstract

The photolysis of a phenanthroline-containing imidazole in a DMSO solution and the initiating ability of the compound in the photopolymerization of multifunctional (meth)acrylates under LED irradiation (λ = 395 nm) in aerobic conditions have been studied for the first time. The relationship between the kinetic parameters of photopolymerization and light intensity and the chemical structure and viscosity of multifunctional monomers has been established.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
High Energy Chemistry
High Energy Chemistry 化学-物理化学
CiteScore
1.50
自引率
28.60%
发文量
62
审稿时长
6-12 weeks
期刊介绍: High Energy Chemistry publishes original articles, reviews, and short communications on molecular and supramolecular photochemistry, photobiology, radiation chemistry, plasma chemistry, chemistry of nanosized systems, chemistry of new atoms, processes and materials for optical information systems and other areas of high energy chemistry. It publishes theoretical and experimental studies in all areas of high energy chemistry, such as the interaction of high-energy particles with matter, the nature and reactivity of short-lived species induced by the action of particle and electromagnetic radiation or hot atoms on substances in their gaseous and condensed states, and chemical processes initiated in organic and inorganic systems by high-energy radiation.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信