Xi‐long Jiang, Xing‐yuan Chen, Fang‐Fang Wang, Ming‐yuan Chien, Hai‐mei Li
{"title":"采用超临界流体发泡注塑技术和不采用气体反压技术成型的小麦秸秆粉/高密度聚乙烯部件的细胞形态和机械性能比较","authors":"Xi‐long Jiang, Xing‐yuan Chen, Fang‐Fang Wang, Ming‐yuan Chien, Hai‐mei Li","doi":"10.1002/pen.26899","DOIUrl":null,"url":null,"abstract":"<jats:label/>Composites were fabricated using maleic anhydride‐grafted high‐density polyethylene as the matrix material and wheat straw as the filler. Differential scanning calorimetry and rheological properties of these composites were investigated to determine the processing parameters for supercritical fluid (SCF) microcellular injection with and without gas counter pressure (GCP) technology. The impacts of different proportions and dimensions of wheat straw, along with process parameters related to GCP, were determined on both the cellular structure and mechanical characteristics of foamed injection molded components. Experimental results revealed that an increase in the ratio of wheat straw and a reduction in its size led to enhancements in both storage modulus and complex viscosity of the composites, while also improving their cell structure when foamed with SCF. By adjusting GCP process parameters, it was possible to regulate both cell morphology and mechanical properties of foamed injection molded parts. Higher GCP or longer GCP holding time resulted in increased skin thickness and tensile strength but decreased notched Izod impact strength.Highlights<jats:list list-type=\"bullet\"> <jats:list-item>Built relations between GCP technology parameters and cell morphologies.</jats:list-item> <jats:list-item>Compared the influence of wheat straw powder and GCP parameters quantitatively.</jats:list-item> <jats:list-item>Explored the correlation between cellular morphology and mechanical properties.</jats:list-item> <jats:list-item>The regulatory mechanism of cell morphology, size ratio, and distribution.</jats:list-item> <jats:list-item>GCP effectively modulates cell morphologies and mechanical properties.</jats:list-item> </jats:list>","PeriodicalId":20281,"journal":{"name":"Polymer Engineering and Science","volume":"3 1","pages":""},"PeriodicalIF":3.2000,"publicationDate":"2024-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Comparison of cell morphology and mechanical properties of wheat straw powder/HDPE parts molded by supercritical fluid foamed injection with and without gas counter pressure technology\",\"authors\":\"Xi‐long Jiang, Xing‐yuan Chen, Fang‐Fang Wang, Ming‐yuan Chien, Hai‐mei Li\",\"doi\":\"10.1002/pen.26899\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<jats:label/>Composites were fabricated using maleic anhydride‐grafted high‐density polyethylene as the matrix material and wheat straw as the filler. Differential scanning calorimetry and rheological properties of these composites were investigated to determine the processing parameters for supercritical fluid (SCF) microcellular injection with and without gas counter pressure (GCP) technology. The impacts of different proportions and dimensions of wheat straw, along with process parameters related to GCP, were determined on both the cellular structure and mechanical characteristics of foamed injection molded components. Experimental results revealed that an increase in the ratio of wheat straw and a reduction in its size led to enhancements in both storage modulus and complex viscosity of the composites, while also improving their cell structure when foamed with SCF. By adjusting GCP process parameters, it was possible to regulate both cell morphology and mechanical properties of foamed injection molded parts. Higher GCP or longer GCP holding time resulted in increased skin thickness and tensile strength but decreased notched Izod impact strength.Highlights<jats:list list-type=\\\"bullet\\\"> <jats:list-item>Built relations between GCP technology parameters and cell morphologies.</jats:list-item> <jats:list-item>Compared the influence of wheat straw powder and GCP parameters quantitatively.</jats:list-item> <jats:list-item>Explored the correlation between cellular morphology and mechanical properties.</jats:list-item> <jats:list-item>The regulatory mechanism of cell morphology, size ratio, and distribution.</jats:list-item> <jats:list-item>GCP effectively modulates cell morphologies and mechanical properties.</jats:list-item> </jats:list>\",\"PeriodicalId\":20281,\"journal\":{\"name\":\"Polymer Engineering and Science\",\"volume\":\"3 1\",\"pages\":\"\"},\"PeriodicalIF\":3.2000,\"publicationDate\":\"2024-07-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polymer Engineering and Science\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1002/pen.26899\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Engineering and Science","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1002/pen.26899","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Comparison of cell morphology and mechanical properties of wheat straw powder/HDPE parts molded by supercritical fluid foamed injection with and without gas counter pressure technology
Composites were fabricated using maleic anhydride‐grafted high‐density polyethylene as the matrix material and wheat straw as the filler. Differential scanning calorimetry and rheological properties of these composites were investigated to determine the processing parameters for supercritical fluid (SCF) microcellular injection with and without gas counter pressure (GCP) technology. The impacts of different proportions and dimensions of wheat straw, along with process parameters related to GCP, were determined on both the cellular structure and mechanical characteristics of foamed injection molded components. Experimental results revealed that an increase in the ratio of wheat straw and a reduction in its size led to enhancements in both storage modulus and complex viscosity of the composites, while also improving their cell structure when foamed with SCF. By adjusting GCP process parameters, it was possible to regulate both cell morphology and mechanical properties of foamed injection molded parts. Higher GCP or longer GCP holding time resulted in increased skin thickness and tensile strength but decreased notched Izod impact strength.HighlightsBuilt relations between GCP technology parameters and cell morphologies.Compared the influence of wheat straw powder and GCP parameters quantitatively.Explored the correlation between cellular morphology and mechanical properties.The regulatory mechanism of cell morphology, size ratio, and distribution.GCP effectively modulates cell morphologies and mechanical properties.
期刊介绍:
For more than 30 years, Polymer Engineering & Science has been one of the most highly regarded journals in the field, serving as a forum for authors of treatises on the cutting edge of polymer science and technology. The importance of PE&S is underscored by the frequent rate at which its articles are cited, especially by other publications - literally thousand of times a year. Engineers, researchers, technicians, and academicians worldwide are looking to PE&S for the valuable information they need. There are special issues compiled by distinguished guest editors. These contain proceedings of symposia on such diverse topics as polyblends, mechanics of plastics and polymer welding.