Wenwen Zhou, Jin Chen, Zhifeng Guo, Jiaqiang Xie, Jiani Wang
{"title":"短碳纤维增强光敏树脂的制备及复合材料性能研究","authors":"Wenwen Zhou, Jin Chen, Zhifeng Guo, Jiaqiang Xie, Jiani Wang","doi":"10.1002/pen.26889","DOIUrl":null,"url":null,"abstract":"<jats:label/>Light‐curing rapid prototyping (SLA) has become an emerging technology in the manufacturing industry because of its high precision, rapid prototyping, and the ability to mold complex parts. To enhance the mechanical properties and thermal stability of its raw material photosensitive resin (PR), carbon fiber (CF) was surface modified by chemical oxidation and grafting of amino silane (KH550) to obtain KH550‐modified carbon fiber (ACF). Then, ACF was composited with photosensitive resin to obtain modified carbon fiber/photosensitive resin (ACF/PR) composites. The viscosities of ACF/PR composites, including the viscosity, curing shrinkage, mechanical properties, and thermal stability of the ACF/PR composites, were characterized. The results showed that KH550 was successfully grafted onto CF. When the addition of ACF in the composites was 0.6%, the tensile strength, elongation at break, and impact strength of ACF/PR reached 39.48 MPa, 20.32%, and 13.62 kJ/m<jats:sup>2</jats:sup>, which were 120%, 27.15%, and 154% higher than that of the pure resin; the thermal decomposition temperatures and the maximum thermal decomposition temperatures at 50% mass loss of ACF/PR increased to 457.66°C and 442.44°C at 50% mass loss, which is 3.95% and 3.63% higher than that of the pure resin. Currently, the composites have excellent strength, toughness, and thermal stability. This paper gives a cost‐efficient method for improving the functioning of PR.Highlights<jats:list list-type=\"bullet\"> <jats:list-item>Mixed acid oxidation and amino silane modification of CFs.</jats:list-item> <jats:list-item>Preparation of modified CF/photosensitive resin composites.</jats:list-item> <jats:list-item>Composites with excellent mechanical properties and thermal stability.</jats:list-item> </jats:list>","PeriodicalId":20281,"journal":{"name":"Polymer Engineering and Science","volume":"26 1","pages":""},"PeriodicalIF":3.2000,"publicationDate":"2024-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Preparation of short carbon fiber reinforced photosensitive resin and composite material properties study\",\"authors\":\"Wenwen Zhou, Jin Chen, Zhifeng Guo, Jiaqiang Xie, Jiani Wang\",\"doi\":\"10.1002/pen.26889\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<jats:label/>Light‐curing rapid prototyping (SLA) has become an emerging technology in the manufacturing industry because of its high precision, rapid prototyping, and the ability to mold complex parts. To enhance the mechanical properties and thermal stability of its raw material photosensitive resin (PR), carbon fiber (CF) was surface modified by chemical oxidation and grafting of amino silane (KH550) to obtain KH550‐modified carbon fiber (ACF). Then, ACF was composited with photosensitive resin to obtain modified carbon fiber/photosensitive resin (ACF/PR) composites. The viscosities of ACF/PR composites, including the viscosity, curing shrinkage, mechanical properties, and thermal stability of the ACF/PR composites, were characterized. The results showed that KH550 was successfully grafted onto CF. When the addition of ACF in the composites was 0.6%, the tensile strength, elongation at break, and impact strength of ACF/PR reached 39.48 MPa, 20.32%, and 13.62 kJ/m<jats:sup>2</jats:sup>, which were 120%, 27.15%, and 154% higher than that of the pure resin; the thermal decomposition temperatures and the maximum thermal decomposition temperatures at 50% mass loss of ACF/PR increased to 457.66°C and 442.44°C at 50% mass loss, which is 3.95% and 3.63% higher than that of the pure resin. Currently, the composites have excellent strength, toughness, and thermal stability. This paper gives a cost‐efficient method for improving the functioning of PR.Highlights<jats:list list-type=\\\"bullet\\\"> <jats:list-item>Mixed acid oxidation and amino silane modification of CFs.</jats:list-item> <jats:list-item>Preparation of modified CF/photosensitive resin composites.</jats:list-item> <jats:list-item>Composites with excellent mechanical properties and thermal stability.</jats:list-item> </jats:list>\",\"PeriodicalId\":20281,\"journal\":{\"name\":\"Polymer Engineering and Science\",\"volume\":\"26 1\",\"pages\":\"\"},\"PeriodicalIF\":3.2000,\"publicationDate\":\"2024-07-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polymer Engineering and Science\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1002/pen.26889\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Engineering and Science","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1002/pen.26889","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Preparation of short carbon fiber reinforced photosensitive resin and composite material properties study
Light‐curing rapid prototyping (SLA) has become an emerging technology in the manufacturing industry because of its high precision, rapid prototyping, and the ability to mold complex parts. To enhance the mechanical properties and thermal stability of its raw material photosensitive resin (PR), carbon fiber (CF) was surface modified by chemical oxidation and grafting of amino silane (KH550) to obtain KH550‐modified carbon fiber (ACF). Then, ACF was composited with photosensitive resin to obtain modified carbon fiber/photosensitive resin (ACF/PR) composites. The viscosities of ACF/PR composites, including the viscosity, curing shrinkage, mechanical properties, and thermal stability of the ACF/PR composites, were characterized. The results showed that KH550 was successfully grafted onto CF. When the addition of ACF in the composites was 0.6%, the tensile strength, elongation at break, and impact strength of ACF/PR reached 39.48 MPa, 20.32%, and 13.62 kJ/m2, which were 120%, 27.15%, and 154% higher than that of the pure resin; the thermal decomposition temperatures and the maximum thermal decomposition temperatures at 50% mass loss of ACF/PR increased to 457.66°C and 442.44°C at 50% mass loss, which is 3.95% and 3.63% higher than that of the pure resin. Currently, the composites have excellent strength, toughness, and thermal stability. This paper gives a cost‐efficient method for improving the functioning of PR.HighlightsMixed acid oxidation and amino silane modification of CFs.Preparation of modified CF/photosensitive resin composites.Composites with excellent mechanical properties and thermal stability.
期刊介绍:
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