短碳纤维增强光敏树脂的制备及复合材料性能研究

IF 3.2 4区 工程技术 Q2 ENGINEERING, CHEMICAL
Wenwen Zhou, Jin Chen, Zhifeng Guo, Jiaqiang Xie, Jiani Wang
{"title":"短碳纤维增强光敏树脂的制备及复合材料性能研究","authors":"Wenwen Zhou, Jin Chen, Zhifeng Guo, Jiaqiang Xie, Jiani Wang","doi":"10.1002/pen.26889","DOIUrl":null,"url":null,"abstract":"<jats:label/>Light‐curing rapid prototyping (SLA) has become an emerging technology in the manufacturing industry because of its high precision, rapid prototyping, and the ability to mold complex parts. To enhance the mechanical properties and thermal stability of its raw material photosensitive resin (PR), carbon fiber (CF) was surface modified by chemical oxidation and grafting of amino silane (KH550) to obtain KH550‐modified carbon fiber (ACF). Then, ACF was composited with photosensitive resin to obtain modified carbon fiber/photosensitive resin (ACF/PR) composites. The viscosities of ACF/PR composites, including the viscosity, curing shrinkage, mechanical properties, and thermal stability of the ACF/PR composites, were characterized. The results showed that KH550 was successfully grafted onto CF. When the addition of ACF in the composites was 0.6%, the tensile strength, elongation at break, and impact strength of ACF/PR reached 39.48 MPa, 20.32%, and 13.62 kJ/m<jats:sup>2</jats:sup>, which were 120%, 27.15%, and 154% higher than that of the pure resin; the thermal decomposition temperatures and the maximum thermal decomposition temperatures at 50% mass loss of ACF/PR increased to 457.66°C and 442.44°C at 50% mass loss, which is 3.95% and 3.63% higher than that of the pure resin. Currently, the composites have excellent strength, toughness, and thermal stability. This paper gives a cost‐efficient method for improving the functioning of PR.Highlights<jats:list list-type=\"bullet\"> <jats:list-item>Mixed acid oxidation and amino silane modification of CFs.</jats:list-item> <jats:list-item>Preparation of modified CF/photosensitive resin composites.</jats:list-item> <jats:list-item>Composites with excellent mechanical properties and thermal stability.</jats:list-item> </jats:list>","PeriodicalId":20281,"journal":{"name":"Polymer Engineering and Science","volume":"26 1","pages":""},"PeriodicalIF":3.2000,"publicationDate":"2024-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Preparation of short carbon fiber reinforced photosensitive resin and composite material properties study\",\"authors\":\"Wenwen Zhou, Jin Chen, Zhifeng Guo, Jiaqiang Xie, Jiani Wang\",\"doi\":\"10.1002/pen.26889\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<jats:label/>Light‐curing rapid prototyping (SLA) has become an emerging technology in the manufacturing industry because of its high precision, rapid prototyping, and the ability to mold complex parts. To enhance the mechanical properties and thermal stability of its raw material photosensitive resin (PR), carbon fiber (CF) was surface modified by chemical oxidation and grafting of amino silane (KH550) to obtain KH550‐modified carbon fiber (ACF). Then, ACF was composited with photosensitive resin to obtain modified carbon fiber/photosensitive resin (ACF/PR) composites. The viscosities of ACF/PR composites, including the viscosity, curing shrinkage, mechanical properties, and thermal stability of the ACF/PR composites, were characterized. The results showed that KH550 was successfully grafted onto CF. When the addition of ACF in the composites was 0.6%, the tensile strength, elongation at break, and impact strength of ACF/PR reached 39.48 MPa, 20.32%, and 13.62 kJ/m<jats:sup>2</jats:sup>, which were 120%, 27.15%, and 154% higher than that of the pure resin; the thermal decomposition temperatures and the maximum thermal decomposition temperatures at 50% mass loss of ACF/PR increased to 457.66°C and 442.44°C at 50% mass loss, which is 3.95% and 3.63% higher than that of the pure resin. Currently, the composites have excellent strength, toughness, and thermal stability. This paper gives a cost‐efficient method for improving the functioning of PR.Highlights<jats:list list-type=\\\"bullet\\\"> <jats:list-item>Mixed acid oxidation and amino silane modification of CFs.</jats:list-item> <jats:list-item>Preparation of modified CF/photosensitive resin composites.</jats:list-item> <jats:list-item>Composites with excellent mechanical properties and thermal stability.</jats:list-item> </jats:list>\",\"PeriodicalId\":20281,\"journal\":{\"name\":\"Polymer Engineering and Science\",\"volume\":\"26 1\",\"pages\":\"\"},\"PeriodicalIF\":3.2000,\"publicationDate\":\"2024-07-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polymer Engineering and Science\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1002/pen.26889\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Engineering and Science","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1002/pen.26889","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
引用次数: 0

摘要

光固化快速成型技术(SLA)因其高精度、快速成型、可成型复杂零件等优点,已成为制造业的一项新兴技术。为提高其原材料光敏树脂(PR)的机械性能和热稳定性,通过化学氧化和接枝氨基硅烷(KH550)对碳纤维(CF)进行表面改性,得到 KH550 改性碳纤维(ACF)。然后,将碳纤维与光敏树脂复合,得到改性碳纤维/光敏树脂(ACF/PR)复合材料。研究人员对 ACF/PR 复合材料的粘度、固化收缩率、机械性能和热稳定性进行了表征。结果表明,KH550 成功接枝到了 CF 上。当复合材料中的 ACF 添加量为 0.6% 时,ACF/PR 的拉伸强度、断裂伸长率和冲击强度分别达到了 39.48 MPa、20.32% 和 13.62 kJ/m2,分别比 CF 高出 120%、27.15% 和 154%。15%和154%;ACF/PR的热分解温度和失重50%时的最大热分解温度分别升至457.66℃和442.44℃,比纯树脂高3.95%和3.63%。目前,该复合材料具有优异的强度、韧性和热稳定性。本文给出了一种改善 PR 功能的经济有效的方法。 亮点 混合酸氧化和氨基硅烷改性 CF。制备改性 CF/光敏树脂复合材料。具有优异机械性能和热稳定性的复合材料。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Preparation of short carbon fiber reinforced photosensitive resin and composite material properties study
Light‐curing rapid prototyping (SLA) has become an emerging technology in the manufacturing industry because of its high precision, rapid prototyping, and the ability to mold complex parts. To enhance the mechanical properties and thermal stability of its raw material photosensitive resin (PR), carbon fiber (CF) was surface modified by chemical oxidation and grafting of amino silane (KH550) to obtain KH550‐modified carbon fiber (ACF). Then, ACF was composited with photosensitive resin to obtain modified carbon fiber/photosensitive resin (ACF/PR) composites. The viscosities of ACF/PR composites, including the viscosity, curing shrinkage, mechanical properties, and thermal stability of the ACF/PR composites, were characterized. The results showed that KH550 was successfully grafted onto CF. When the addition of ACF in the composites was 0.6%, the tensile strength, elongation at break, and impact strength of ACF/PR reached 39.48 MPa, 20.32%, and 13.62 kJ/m2, which were 120%, 27.15%, and 154% higher than that of the pure resin; the thermal decomposition temperatures and the maximum thermal decomposition temperatures at 50% mass loss of ACF/PR increased to 457.66°C and 442.44°C at 50% mass loss, which is 3.95% and 3.63% higher than that of the pure resin. Currently, the composites have excellent strength, toughness, and thermal stability. This paper gives a cost‐efficient method for improving the functioning of PR.Highlights Mixed acid oxidation and amino silane modification of CFs. Preparation of modified CF/photosensitive resin composites. Composites with excellent mechanical properties and thermal stability.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Polymer Engineering and Science
Polymer Engineering and Science 工程技术-高分子科学
CiteScore
5.40
自引率
18.80%
发文量
329
审稿时长
3.7 months
期刊介绍: For more than 30 years, Polymer Engineering & Science has been one of the most highly regarded journals in the field, serving as a forum for authors of treatises on the cutting edge of polymer science and technology. The importance of PE&S is underscored by the frequent rate at which its articles are cited, especially by other publications - literally thousand of times a year. Engineers, researchers, technicians, and academicians worldwide are looking to PE&S for the valuable information they need. There are special issues compiled by distinguished guest editors. These contain proceedings of symposia on such diverse topics as polyblends, mechanics of plastics and polymer welding.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信