Tobias Mayer, Peter Mayer, Hans-Christian Böttcher
{"title":"重氮盐加入二核有机钌络合物的配位不饱和核心","authors":"Tobias Mayer, Peter Mayer, Hans-Christian Böttcher","doi":"10.1515/znb-2024-0006","DOIUrl":null,"url":null,"abstract":"The reaction of [Ru<jats:sub>2</jats:sub>(CO)<jats:sub>4</jats:sub>(<jats:italic>µ</jats:italic>-H)(<jats:italic>µ</jats:italic>-P<jats:italic>t</jats:italic>Bu<jats:sub>2</jats:sub>)(<jats:italic>µ</jats:italic>-Ph<jats:sub>2</jats:sub>PCH<jats:sub>2</jats:sub>PPh<jats:sub>2</jats:sub>)] (1) with the diazonium salts [PhN<jats:sub>2</jats:sub>]BF<jats:sub>4</jats:sub> and [<jats:italic>p</jats:italic>-BrC<jats:sub>6</jats:sub>H<jats:sub>4</jats:sub>N<jats:sub>2</jats:sub>]BF<jats:sub>4</jats:sub> in dichloromethane at <jats:italic>T</jats:italic> = 273 K was investigated. The oxidative addition afforded the products [Ru<jats:sub>2</jats:sub>(CO)<jats:sub>4</jats:sub>(<jats:italic>µ</jats:italic>-H)(<jats:italic>µ</jats:italic>-P<jats:italic>t</jats:italic>Bu<jats:sub>2</jats:sub>)(<jats:italic>µ</jats:italic>-Ph<jats:sub>2</jats:sub>PCH<jats:sub>2</jats:sub>PPh<jats:sub>2</jats:sub>)(<jats:italic>µ</jats:italic>-N<jats:sub>2</jats:sub>Ph)]BF<jats:sub>4</jats:sub> (2a) and [Ru<jats:sub>2</jats:sub>(CO)<jats:sub>4</jats:sub>(<jats:italic>µ</jats:italic>-H)(<jats:italic>µ</jats:italic>-P<jats:italic>t</jats:italic>Bu<jats:sub>2</jats:sub>)(<jats:italic>µ</jats:italic>-Ph<jats:sub>2</jats:sub>PCH<jats:sub>2</jats:sub>PPh<jats:sub>2</jats:sub>)(<jats:italic>µ</jats:italic>-N<jats:sub>2</jats:sub>C<jats:sub>6</jats:sub>H<jats:sub>4</jats:sub>-<jats:italic>p</jats:italic>-Br)]BF<jats:sub>4</jats:sub> (2b) in good yields. The products have been characterized by NMR and IR spectroscopy and mass spectrometry and the molecular structure of 2a has been determined by a single-crystal X-ray diffraction analysis (monoclinic, space group <jats:italic>P</jats:italic>2<jats:sub>1</jats:sub>/<jats:italic>m</jats:italic>, <jats:italic>Z</jats:italic> = 2).","PeriodicalId":23831,"journal":{"name":"Zeitschrift für Naturforschung B","volume":"52 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-07-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Addition of diazonium salts to the coordinatively unsaturated core of a dinuclear organoruthenium complex\",\"authors\":\"Tobias Mayer, Peter Mayer, Hans-Christian Böttcher\",\"doi\":\"10.1515/znb-2024-0006\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The reaction of [Ru<jats:sub>2</jats:sub>(CO)<jats:sub>4</jats:sub>(<jats:italic>µ</jats:italic>-H)(<jats:italic>µ</jats:italic>-P<jats:italic>t</jats:italic>Bu<jats:sub>2</jats:sub>)(<jats:italic>µ</jats:italic>-Ph<jats:sub>2</jats:sub>PCH<jats:sub>2</jats:sub>PPh<jats:sub>2</jats:sub>)] (1) with the diazonium salts [PhN<jats:sub>2</jats:sub>]BF<jats:sub>4</jats:sub> and [<jats:italic>p</jats:italic>-BrC<jats:sub>6</jats:sub>H<jats:sub>4</jats:sub>N<jats:sub>2</jats:sub>]BF<jats:sub>4</jats:sub> in dichloromethane at <jats:italic>T</jats:italic> = 273 K was investigated. The oxidative addition afforded the products [Ru<jats:sub>2</jats:sub>(CO)<jats:sub>4</jats:sub>(<jats:italic>µ</jats:italic>-H)(<jats:italic>µ</jats:italic>-P<jats:italic>t</jats:italic>Bu<jats:sub>2</jats:sub>)(<jats:italic>µ</jats:italic>-Ph<jats:sub>2</jats:sub>PCH<jats:sub>2</jats:sub>PPh<jats:sub>2</jats:sub>)(<jats:italic>µ</jats:italic>-N<jats:sub>2</jats:sub>Ph)]BF<jats:sub>4</jats:sub> (2a) and [Ru<jats:sub>2</jats:sub>(CO)<jats:sub>4</jats:sub>(<jats:italic>µ</jats:italic>-H)(<jats:italic>µ</jats:italic>-P<jats:italic>t</jats:italic>Bu<jats:sub>2</jats:sub>)(<jats:italic>µ</jats:italic>-Ph<jats:sub>2</jats:sub>PCH<jats:sub>2</jats:sub>PPh<jats:sub>2</jats:sub>)(<jats:italic>µ</jats:italic>-N<jats:sub>2</jats:sub>C<jats:sub>6</jats:sub>H<jats:sub>4</jats:sub>-<jats:italic>p</jats:italic>-Br)]BF<jats:sub>4</jats:sub> (2b) in good yields. The products have been characterized by NMR and IR spectroscopy and mass spectrometry and the molecular structure of 2a has been determined by a single-crystal X-ray diffraction analysis (monoclinic, space group <jats:italic>P</jats:italic>2<jats:sub>1</jats:sub>/<jats:italic>m</jats:italic>, <jats:italic>Z</jats:italic> = 2).\",\"PeriodicalId\":23831,\"journal\":{\"name\":\"Zeitschrift für Naturforschung B\",\"volume\":\"52 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-07-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Zeitschrift für Naturforschung B\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1515/znb-2024-0006\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Zeitschrift für Naturforschung B","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1515/znb-2024-0006","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
研究了[Ru2(CO)4(µ-H)(µ-PtBu2)(µ-Ph2PCH2PPh2)](1)与重氮盐[PhN2]BF4 和[p-BrC6H4N2]BF4 在二氯甲烷中于 T = 273 K 的反应。氧化加成产物为[Ru2(CO)4(µ-H)(µ-PtBu2)(µ-Ph2PCH2PPh2)(µ-N2Ph)]BF4（2a）和[Ru2(CO)4(µ-H)(µ-PtBu2)(µ-Ph2PCH2PPh2)(µ-N2C6H4-p-Br)]BF4（2b），收率良好。这些产物已通过核磁共振、红外光谱和质谱法进行了表征，2a 的分子结构已通过单晶 X 射线衍射分析（单斜，空间群 P21/m，Z = 2）确定。
Addition of diazonium salts to the coordinatively unsaturated core of a dinuclear organoruthenium complex
The reaction of [Ru2(CO)4(µ-H)(µ-PtBu2)(µ-Ph2PCH2PPh2)] (1) with the diazonium salts [PhN2]BF4 and [p-BrC6H4N2]BF4 in dichloromethane at T = 273 K was investigated. The oxidative addition afforded the products [Ru2(CO)4(µ-H)(µ-PtBu2)(µ-Ph2PCH2PPh2)(µ-N2Ph)]BF4 (2a) and [Ru2(CO)4(µ-H)(µ-PtBu2)(µ-Ph2PCH2PPh2)(µ-N2C6H4-p-Br)]BF4 (2b) in good yields. The products have been characterized by NMR and IR spectroscopy and mass spectrometry and the molecular structure of 2a has been determined by a single-crystal X-ray diffraction analysis (monoclinic, space group P21/m, Z = 2).
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