Characterizing Hydrated Sulfates and Altered Phases in Jezero Crater Fan and Floor Geologic Units With SHERLOC on Mars 2020

The Mars 2020 Perseverance rover has explored fluvio-lacustrine sedimentary rocks within Jezero crater. Prior work showed that igneous crater floor Séítah and Máaz formations have mafic mineralogy with alteration phases that indicate multiple episodes of aqueous alteration. In this work, we extend the analyses of hydration to targets in the Jezero western fan delta, using data from the SHERLOC (Scanning Habitable Environments with Raman and Luminescence for Organics and Chemicals) Raman spectrometer. Spectral features, for example, sulfate and hydration peak positions and shapes, vary within, and across the crater floor and western fan. The proportion of targets with hydration associated with sulfates was approximately equal in the crater floor and the western fan. All hydrated targets in the crater floor and upper fan showed bimodal hydration peaks at ∼3,200 and ∼3,400 cm⁻¹. The sulfate symmetric stretch at ∼1,000 cm⁻¹ coupled with a hydration peak at ∼3,400 cm⁻¹ indicate that MgSO₄·nH₂O (2 < n ≤ 5) is a likely hydration carrier phase in all units, perhaps paired with low-hydration (n ≤ 1) amorphous Mg-sulfates, indicated by the ∼3,200 cm⁻¹ peak. Low-hydration MgSO₄·nH₂O (n = 1–2) are more prevalent in the fan, and hydrated targets in the fan front only had one peak at ∼3,400 cm⁻¹. While anhydrite co-occurs with hydrated Mg-sulfates in the crater floor and fan front, hydrated Ca-sulfates are observed instead at the top of the upper fan. Collectively, the data imply aqueous deposition of sediments with formation of salts from high ionic strength fluids and subsequent aridity to preserve the observed hydration states.