A. Opekunov, M. Opekunova, S. Kukushkin, S. Janson
{"title":"纳定姆-普尔交汇处(西伯利亚西部北部)人为干扰地区雪盖的矿物学和地球化学参数","authors":"A. Opekunov, M. Opekunova, S. Kukushkin, S. Janson","doi":"10.55959/msu0579-9414.5.79.3.2","DOIUrl":null,"url":null,"abstract":"The article analyzes the content of metals in solid aerosols and snow water sampled in the anthropogeni-cally disturbed and background sites of the Nadym-Pur interfluve. The results of microscopic studies of solid aerosols showed the presence of secondary minerals, technogenic formations, as well as a large amount of pyrite in samples from the eastern part of the study area. The maximum concentrations of metals in solid aero-sols were found in snow of the sanitary protection zones of waste disposal facilities, with the exception of Ca, which prevails in snow cover of Novy Urengoy (up to 10% of dry matter). The urbanized area is characterized by the highest values of dust load (up to 111 mg/m2 a day). The local contamination with Ba within the waste landfills in Novy Urengoy is associated with the sites of barite and drilling waste processing. We applied the factor analysis to identify the main metal associations characteristic of solid aerosols from different functional zones: Ca-Co-V-Mn (city), Ba-Sr-K-Na and Cd-Cu-Pb (waste disposal sites), Cu-Ni-Cd (the entire studied area). Based on the study of the content of dissolved forms in snow water, a high mobility of metals in the northern landscapes and its decrease in urban environment were revealed. The mineralogical and geochemical analysis of snow suggests the influence of the Norilsk industrial region on the eastern part of the Nadym-Pur interfluve, Zn, Cu, Ni, Pb and the mineral pyrite being the indicators. The risks of environmental pollution under the aerotechnogenic transport are associated with high content of Zn, Cu, Ni, Pb and Ba in solid aero-sols. The calculation of the Toxicity Probability Index (MERMQ) showed that some aerosol samples from the landfill sites have a high probability of biological effects. Using data on the chemical composition of soils and soil water, no visible effect of snow pollution on the growth of metal concentrations in soil and soil water was revealed, with the exception of local contamination with Ba, which led to a twofold increase in the content of the metal in the upper soil horizon.","PeriodicalId":158808,"journal":{"name":"Lomonosov Geography Journal","volume":"55 s62","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"MINERALOGICAL AND GEOCHEMICAL PARAMETERS OF SNOW COVER WITHIN THE ANTHROPOGENICALLY DISTURBED SITES OF THE NADYM-PUR INTERFLUVE (NORTHERN PART OF WESTERN SIBERIA)\",\"authors\":\"A. Opekunov, M. Opekunova, S. Kukushkin, S. Janson\",\"doi\":\"10.55959/msu0579-9414.5.79.3.2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The article analyzes the content of metals in solid aerosols and snow water sampled in the anthropogeni-cally disturbed and background sites of the Nadym-Pur interfluve. The results of microscopic studies of solid aerosols showed the presence of secondary minerals, technogenic formations, as well as a large amount of pyrite in samples from the eastern part of the study area. The maximum concentrations of metals in solid aero-sols were found in snow of the sanitary protection zones of waste disposal facilities, with the exception of Ca, which prevails in snow cover of Novy Urengoy (up to 10% of dry matter). The urbanized area is characterized by the highest values of dust load (up to 111 mg/m2 a day). The local contamination with Ba within the waste landfills in Novy Urengoy is associated with the sites of barite and drilling waste processing. We applied the factor analysis to identify the main metal associations characteristic of solid aerosols from different functional zones: Ca-Co-V-Mn (city), Ba-Sr-K-Na and Cd-Cu-Pb (waste disposal sites), Cu-Ni-Cd (the entire studied area). Based on the study of the content of dissolved forms in snow water, a high mobility of metals in the northern landscapes and its decrease in urban environment were revealed. The mineralogical and geochemical analysis of snow suggests the influence of the Norilsk industrial region on the eastern part of the Nadym-Pur interfluve, Zn, Cu, Ni, Pb and the mineral pyrite being the indicators. The risks of environmental pollution under the aerotechnogenic transport are associated with high content of Zn, Cu, Ni, Pb and Ba in solid aero-sols. The calculation of the Toxicity Probability Index (MERMQ) showed that some aerosol samples from the landfill sites have a high probability of biological effects. 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引用次数: 0
摘要
文章分析了在纳定姆-普尔交汇处受人为干扰的地点和背景地点采样的固体气溶胶和雪水中的金属含量。固体气溶胶的显微研究结果表明,在研究区东部的样本中存在次生矿物、技术形成物以及大量黄铁矿。固体气溶胶中金属浓度最高的地方是垃圾处理设施卫生保护区的积雪,但 Ca 除外,在新乌联戈伊的积雪中普遍存在(达到干物质的 10%)。城市化地区的粉尘量最高(每天高达 111 毫克/平方米)。新乌连可伊垃圾填埋场内的局部钡污染与重晶石和钻探废料加工场所有关。我们运用因子分析确定了不同功能区固体气溶胶的主要金属关联特征:Ca-Co-V-Mn(城市)、Ba-Sr-K-Na 和 Cd-Cu-Pb(废物处理场)、Cu-Ni-Cd(整个研究区域)。根据对雪水中溶解形式含量的研究,发现金属在北部地貌中的流动性较高,而在城市环境中的流动性较低。雪的矿物学和地球化学分析表明,诺里尔斯克工业区对纳定姆-普尔交汇处东部地区产生了影响,锌、铜、镍、铅和矿物黄铁矿是影响指标。气溶胶固体中的锌、铜、镍、铅和钡含量较高,这与航空运输造成的环境污染风险有关。毒性概率指数(MERMQ)的计算表明,垃圾填埋场的一些气溶胶样本具有很高的生物效应概率。利用土壤和土壤水的化学成分数据,除了钡的局部污染导致土壤上层的金属含量增加了两倍之外,没有发现雪污染对土壤和土壤水中金属浓度的增长有明显影响。
MINERALOGICAL AND GEOCHEMICAL PARAMETERS OF SNOW COVER WITHIN THE ANTHROPOGENICALLY DISTURBED SITES OF THE NADYM-PUR INTERFLUVE (NORTHERN PART OF WESTERN SIBERIA)
The article analyzes the content of metals in solid aerosols and snow water sampled in the anthropogeni-cally disturbed and background sites of the Nadym-Pur interfluve. The results of microscopic studies of solid aerosols showed the presence of secondary minerals, technogenic formations, as well as a large amount of pyrite in samples from the eastern part of the study area. The maximum concentrations of metals in solid aero-sols were found in snow of the sanitary protection zones of waste disposal facilities, with the exception of Ca, which prevails in snow cover of Novy Urengoy (up to 10% of dry matter). The urbanized area is characterized by the highest values of dust load (up to 111 mg/m2 a day). The local contamination with Ba within the waste landfills in Novy Urengoy is associated with the sites of barite and drilling waste processing. We applied the factor analysis to identify the main metal associations characteristic of solid aerosols from different functional zones: Ca-Co-V-Mn (city), Ba-Sr-K-Na and Cd-Cu-Pb (waste disposal sites), Cu-Ni-Cd (the entire studied area). Based on the study of the content of dissolved forms in snow water, a high mobility of metals in the northern landscapes and its decrease in urban environment were revealed. The mineralogical and geochemical analysis of snow suggests the influence of the Norilsk industrial region on the eastern part of the Nadym-Pur interfluve, Zn, Cu, Ni, Pb and the mineral pyrite being the indicators. The risks of environmental pollution under the aerotechnogenic transport are associated with high content of Zn, Cu, Ni, Pb and Ba in solid aero-sols. The calculation of the Toxicity Probability Index (MERMQ) showed that some aerosol samples from the landfill sites have a high probability of biological effects. Using data on the chemical composition of soils and soil water, no visible effect of snow pollution on the growth of metal concentrations in soil and soil water was revealed, with the exception of local contamination with Ba, which led to a twofold increase in the content of the metal in the upper soil horizon.