提高基于状态方程计算氦气超压缩系数的精度

E.S. Ivanaevskaya, V. Malyshev, E. Moiseeva
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摘要

迄今为止,俄罗斯天然气工业正在开发大量提取的天然气成分中氦含量较高的矿藏,例如恰扬金斯克耶、科维金斯克耶、亚拉克金斯克耶石油和天然气凝析油田。氦气在采集和处理过程中从未被详细研究过,但如今氦气已成为一种重要资源,被广泛应用于军事工业、医药、造船、激光技术、航天技术等领域。对所提取气体中氦气成分的高需求要求创造出一种将氦气从气体中分离出来的技术。此外,氦气是一种 "冷 "气体,因为其分子间的相互作用很弱,所以很难模拟极低温下的相平衡。因此,改进氦气混合物的凝结模拟无疑是当今业界的一项紧迫任务。本研究的目的是根据彭-罗宾逊状态方程在热压条件下对应氦液化过程的修正之一,提高计算氦热力学性质的准确性。作为本工作中使用的方法,在 Java 编程语言中实现了一个计算彭罗修正选择的软件模块。结果在已知的实验数据以及计算流体热力学性质的专用软件产品上进行了测试,并介绍了基于立方状态方程计算氦的超导系数的特点。介绍了根据立方状态方程计算氦的超导系数的特点,找到了彭-罗宾逊状态方程的彭尼洛修正的最佳范围,以及一个可以在低温区域找到修正的近似公式。所获得的结果将使我们能够高精度地计算氦的热力学性质。这将使我们能够预测从天然气中生产和凝结氦的数量,而这无疑是国家经济发展的一项重要任务。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
IMPROVING THE ACCURACY OF CALCULATING THE SUPER-COMPRESSIBILITY COEFFICIENT OF HELIUM BASED ON STATE EQUATIONS
To date, the Russian gas industry is developing a large number of deposits with a high helium content in the composition of the extracted gas, such as Chayandinskoye, Kovyktinskoye, Yaraktinskoye oil and gas condensate fields. Helium has never before been the object of detailed study during gathering and treatment, but today helium is an important resource that is used in many fields: military industry, medicine, shipbuilding, laser technology, space technology. The high demand for the component of the extracted gas has created requirements for the creation of a technology for separating it from gas. In addition, helium is a «cold» gas due to the weak interaction of its molecules, so it is difficult to model phase equilibrium at extremely low temperatures. As a result, improving the simulation of condensation of a helium mixture is undoubtedly an urgent task of the industry today. The purpose of the study is to increase the accuracy of calculating the thermodynamic properties of helium based on one of the modifications of the Peng-Robinson equation of state for thermobaric conditions corresponding to helium liquefaction processes.As the methods used in this work, a software module for calculating the selection of the Peneloux correction in the Java programming language was implemented. The results are tested on known experimental data, as well as a specialized software product for calculating the thermodynamic properties of fluids.The features of calculating the superconductivity coefficient of helium based on the cubic equation of state are presented. The optimal range of the Peneloux correction for the Peng-Robinson equation of state has been found, as well as an approximation formula that allows us to find the correction in the low temperature region. The results obtained will allow us to calculate the thermodynamic properties of helium with high accuracy. This will allow us to predict the volume of production and condensation of helium from natural gas, which is certainly an important task for the development of the country's economy.
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