V. Aslamova, E. Golovkova, E. A. Shneygelberger, A. Aslamov
{"title":"木质素基含硫吸附剂对汞阳离子吸附的规律性","authors":"V. Aslamova, E. Golovkova, E. A. Shneygelberger, A. Aslamov","doi":"10.21285/achb.923","DOIUrl":null,"url":null,"abstract":" The unfavorable environmental situation in the town of Usolye-Sibirskoye (Irkutsk Oblast, Russia) determines the relevance of investigating and applying a new lignin-based sulfur-containing sorbent for purification of groundwater from mercury compounds. The sorbent was synthesized on the basis of waste products of epichlorohydrin (1,2,3-trichloropropane), sulfur, and lignin. The IR spectrum of the sorbent under study showed the presence of an S–S bond in the region of 445–465 cm-1. Intensive absorption of Hg2+ ions in the regions of 2800–2950 cm-1 (valence vibrations of C–H bonds in CH and CH2 groups) and 1460 cm-1 (deformation vibrations in CH2 group) was observed. Absorption of Hg2+ ions by lignin fragments was accompanied by a change in the vibration band of S–S bonds, which splits into two bands of higher frequencies than the νS–S band in the original sorbent. The optimum sulfur content, which ensures the maximum sorption activity of the sorbent, was found to be 53.25%. The mercury sorption isotherms at 20 and 60 °C are described by parabolic dependencies with determination coefficients of 98.9 and 98.6 %, respectively. The kinetic curve at 20 °C and 40 °C is approximated by a hyperbola and a cubic polynomial with determination coefficients of 97.9 and 96.2 %, respectively. The reaction order (first order at 20 °C and second order at 40 °C) and the reaction rate constant (0.0876 min-1 at 20 °C and 0.00014 min-1 at 40 °C) were determined. At 20 °C, the sorption rate of Hg2+ was established to be significantly higher and the sorption time to be faster than those at 40 °C. Therefore, mercury sorption by the proposed sorbent should be carried out at 20 °C in order to reduce energy consumption.","PeriodicalId":20677,"journal":{"name":"Proceedings of Universities. Applied Chemistry and Biotechnology","volume":" 4","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-07-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Regularities in mercury cation sorption by a lignin-based sulfur-containing sorbent\",\"authors\":\"V. Aslamova, E. Golovkova, E. A. Shneygelberger, A. Aslamov\",\"doi\":\"10.21285/achb.923\",\"DOIUrl\":null,\"url\":null,\"abstract\":\" The unfavorable environmental situation in the town of Usolye-Sibirskoye (Irkutsk Oblast, Russia) determines the relevance of investigating and applying a new lignin-based sulfur-containing sorbent for purification of groundwater from mercury compounds. The sorbent was synthesized on the basis of waste products of epichlorohydrin (1,2,3-trichloropropane), sulfur, and lignin. The IR spectrum of the sorbent under study showed the presence of an S–S bond in the region of 445–465 cm-1. Intensive absorption of Hg2+ ions in the regions of 2800–2950 cm-1 (valence vibrations of C–H bonds in CH and CH2 groups) and 1460 cm-1 (deformation vibrations in CH2 group) was observed. Absorption of Hg2+ ions by lignin fragments was accompanied by a change in the vibration band of S–S bonds, which splits into two bands of higher frequencies than the νS–S band in the original sorbent. The optimum sulfur content, which ensures the maximum sorption activity of the sorbent, was found to be 53.25%. The mercury sorption isotherms at 20 and 60 °C are described by parabolic dependencies with determination coefficients of 98.9 and 98.6 %, respectively. The kinetic curve at 20 °C and 40 °C is approximated by a hyperbola and a cubic polynomial with determination coefficients of 97.9 and 96.2 %, respectively. The reaction order (first order at 20 °C and second order at 40 °C) and the reaction rate constant (0.0876 min-1 at 20 °C and 0.00014 min-1 at 40 °C) were determined. At 20 °C, the sorption rate of Hg2+ was established to be significantly higher and the sorption time to be faster than those at 40 °C. Therefore, mercury sorption by the proposed sorbent should be carried out at 20 °C in order to reduce energy consumption.\",\"PeriodicalId\":20677,\"journal\":{\"name\":\"Proceedings of Universities. Applied Chemistry and Biotechnology\",\"volume\":\" 4\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-07-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Proceedings of Universities. Applied Chemistry and Biotechnology\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.21285/achb.923\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Proceedings of Universities. Applied Chemistry and Biotechnology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.21285/achb.923","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
俄罗斯伊尔库茨克州乌苏里耶-西伯利亚镇的不利环境状况决定了研究和应用新型木质素基含硫吸附剂净化地下水中汞化合物的重要性。 这种吸附剂是在环氧氯丙烷(1,2,3-三氯丙烷)废品、硫和木质素的基础上合成的。研究中的吸附剂的红外光谱显示,在 445-465 cm-1 区域存在一个 S-S 键。在 2800-2950 cm-1(CH 和 CH2 基团中 C-H 键的价振动)和 1460 cm-1(CH2 基团中的变形振动)区域观察到 Hg2+ 离子的强烈吸收。木质素碎片对 Hg2+ 离子的吸收伴随着 S-S 键振动带的变化,它分成两个频率高于原始吸附剂中 νS-S 波段的波段。研究发现,确保吸附剂具有最大吸附活性的最佳硫含量为 53.25%。汞在 20 °C 和 60 °C 时的吸附等温线呈抛物线关系,确定系数分别为 98.9% 和 98.6%。20 °C 和 40 °C 时的动力学曲线近似于双曲线和三次多项式,确定系数分别为 97.9% 和 96.2%。测定了反应阶次(20 °C 时为一阶,40 °C 时为二阶)和反应速率常数(20 °C 时为 0.0876 min-1 ,40 °C 时为 0.00014 min-1)。与 40 °C 时相比,20 °C 时 Hg2+ 的吸附速率明显更高,吸附时间也更快。因此,拟议的吸附剂应在 20 °C 下进行汞吸附,以降低能耗。
Regularities in mercury cation sorption by a lignin-based sulfur-containing sorbent
The unfavorable environmental situation in the town of Usolye-Sibirskoye (Irkutsk Oblast, Russia) determines the relevance of investigating and applying a new lignin-based sulfur-containing sorbent for purification of groundwater from mercury compounds. The sorbent was synthesized on the basis of waste products of epichlorohydrin (1,2,3-trichloropropane), sulfur, and lignin. The IR spectrum of the sorbent under study showed the presence of an S–S bond in the region of 445–465 cm-1. Intensive absorption of Hg2+ ions in the regions of 2800–2950 cm-1 (valence vibrations of C–H bonds in CH and CH2 groups) and 1460 cm-1 (deformation vibrations in CH2 group) was observed. Absorption of Hg2+ ions by lignin fragments was accompanied by a change in the vibration band of S–S bonds, which splits into two bands of higher frequencies than the νS–S band in the original sorbent. The optimum sulfur content, which ensures the maximum sorption activity of the sorbent, was found to be 53.25%. The mercury sorption isotherms at 20 and 60 °C are described by parabolic dependencies with determination coefficients of 98.9 and 98.6 %, respectively. The kinetic curve at 20 °C and 40 °C is approximated by a hyperbola and a cubic polynomial with determination coefficients of 97.9 and 96.2 %, respectively. The reaction order (first order at 20 °C and second order at 40 °C) and the reaction rate constant (0.0876 min-1 at 20 °C and 0.00014 min-1 at 40 °C) were determined. At 20 °C, the sorption rate of Hg2+ was established to be significantly higher and the sorption time to be faster than those at 40 °C. Therefore, mercury sorption by the proposed sorbent should be carried out at 20 °C in order to reduce energy consumption.