Zheyao Li, Lei Ju, Ruipeng Bao, Xinbo Lin, Teng Wang, Xinhong Yu
{"title":"N-杂环碳烯催化的二苄基醚再组装:轻松获得α-羟基酮","authors":"Zheyao Li, Lei Ju, Ruipeng Bao, Xinbo Lin, Teng Wang, Xinhong Yu","doi":"10.1055/a-2367-2572","DOIUrl":null,"url":null,"abstract":"A novel one-pot cascade process of oxidation-initiated N-heterocyclic carbene-catalyzed reintegration of dibenzyl ethers has been developed for the first time. This protocol allows straightforward access to α-hydroxy ketones from dibenzyl ethers. It is noteworthy that the present method is the first attempt to synthesize benzoin by utilization of dibenzyl ethers.","PeriodicalId":509029,"journal":{"name":"Synlett","volume":"5 10","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"N-heterocyclic carbene-catalyzed reassembling of dibenzyl ethers: facile access to α-hydroxy ketones\",\"authors\":\"Zheyao Li, Lei Ju, Ruipeng Bao, Xinbo Lin, Teng Wang, Xinhong Yu\",\"doi\":\"10.1055/a-2367-2572\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A novel one-pot cascade process of oxidation-initiated N-heterocyclic carbene-catalyzed reintegration of dibenzyl ethers has been developed for the first time. This protocol allows straightforward access to α-hydroxy ketones from dibenzyl ethers. It is noteworthy that the present method is the first attempt to synthesize benzoin by utilization of dibenzyl ethers.\",\"PeriodicalId\":509029,\"journal\":{\"name\":\"Synlett\",\"volume\":\"5 10\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-07-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synlett\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1055/a-2367-2572\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synlett","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1055/a-2367-2572","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
N-heterocyclic carbene-catalyzed reassembling of dibenzyl ethers: facile access to α-hydroxy ketones
A novel one-pot cascade process of oxidation-initiated N-heterocyclic carbene-catalyzed reintegration of dibenzyl ethers has been developed for the first time. This protocol allows straightforward access to α-hydroxy ketones from dibenzyl ethers. It is noteworthy that the present method is the first attempt to synthesize benzoin by utilization of dibenzyl ethers.