铜催化二炔基乙酸酯与氢磷酸化合物的 C-P 偶联反应，生成磷酸化烯炔类化合物

IF 4.6 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Chemistry Frontiers Pub Date : 2024-07-10 DOI:10.1039/D4QO01021C

Shaoqing Liu, Kaixin Yin, Yishuai Fan, Li-Biao Han and Ruwei Shen

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引用次数: 0

摘要

基于铜-亚铜烯类中间体的位点选择性亲核截取概念，开发了一种高效的铜催化乙酸二炔酯与氢磷酰化合物的偶联反应。该反应提供了一种快速合成新型共轭别炔基磷酰化合物的方法，可在温和的条件下利用现成的材料获得良好至高产率。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Copper-catalyzed allenynylative C–P coupling of diynylic acetates with hydrophosphoryl compounds leading to phosphorylated allenynes†

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Copper-catalyzed allenynylative C–P coupling of diynylic acetates with hydrophosphoryl compounds leading to phosphorylated allenynes†

A highly efficient copper-catalyzed coupling reaction of diynylic acetates with hydrophosphoryl compounds is developed based on the concept of site-selective nucleophilic interception of copper-cumulenylidene-type intermediates. This reaction enables an expeditious synthesis of a novel class of conjugated allenynylphosphoryl compounds in good to high yields from readily available materials under mild conditions.

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来源期刊

Organic Chemistry Frontiers CHEMISTRY, ORGANIC-

CiteScore

7.90

自引率

11.10%

发文量

686

审稿时长

1 months

期刊介绍： Organic Chemistry Frontiers is an esteemed journal that publishes high-quality research across the field of organic chemistry. It places a significant emphasis on studies that contribute substantially to the field by introducing new or significantly improved protocols and methodologies. The journal covers a wide array of topics which include, but are not limited to, organic synthesis, the development of synthetic methodologies, catalysis, natural products, functional organic materials, supramolecular and macromolecular chemistry, as well as physical and computational organic chemistry.