{"title":"印度南部库尔格山的铬-钒-钛磁铁矿(礁石)的起源和热演化","authors":"","doi":"10.1016/j.chemer.2024.126142","DOIUrl":null,"url":null,"abstract":"<div><p><span><span><span><span>This study deals with petrology<span>, textural, thermometry, and geochemical characterization of naturally magnetized Cr-V-Ti magnetite deposits within the layered mafic-ultramafic intrusions in Coorg massif of southern India using ore petrography and mineral/whole rock geochemistry. These deposits, also known as ‘lodestones’, occur as rhythmic layers within the lateritized host rock, with the underlying basement distinguished by the presence of </span></span>charnockites<span><span> and layered gabbro-anorthosites and pyroxenites<span>, delineating a stratified intrusive setting. Lodestones exhibit complex mineral assemblage involving magnetite, ilmenite, ulvöspinel, spinel, corundum, hematite, </span></span>goethite, pyrite, </span></span>pyrrhotite<span>, and amphiboles. The bulk rock chemistry of the lodestone is analogues to Fe-Ti magnetite </span></span>iron ore<span> deposits with elevated vanadium and chromium contents. Their resemblance to tholeiitic magma-type suggests their formation in a layered intrusive setting, evolved through multiple fractional crystallization under oxidizing conditions. Thermometric and fugacity calculations using different textural associations estimate the magmatic fractional crystallization stage at elevated temperatures (601–704 °C) and low </span></span><em>f</em>O<sub>2</sub><span> (−18.6 to −15.3), succeeded by the exsolution stage during subsolidus cooling at lower temperatures (379–540 °C) and high </span><em>f</em>O<sub>2</sub><span> (−38.2 to −22.1). The whole sequence of formation and evolution of lodestone encompasses primary magmatic crystallization, subsolidus re-equilibration, metamorphism, and secondary weathering. The study also suggests a genetic linkage of lodestone with the associated mafic-ultramafic units, depicting two possible magmatic processes either through slab melting and fractional crystallization associated with subduction or due to plume magmatism and associated rifting.</span></p></div>","PeriodicalId":55973,"journal":{"name":"Chemie Der Erde-Geochemistry","volume":"84 3","pages":"Article 126142"},"PeriodicalIF":2.6000,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Origin and thermal evolution of Cr-V-Ti magnetites (lodestones) from Coorg massif, southern India\",\"authors\":\"\",\"doi\":\"10.1016/j.chemer.2024.126142\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p><span><span><span><span>This study deals with petrology<span>, textural, thermometry, and geochemical characterization of naturally magnetized Cr-V-Ti magnetite deposits within the layered mafic-ultramafic intrusions in Coorg massif of southern India using ore petrography and mineral/whole rock geochemistry. These deposits, also known as ‘lodestones’, occur as rhythmic layers within the lateritized host rock, with the underlying basement distinguished by the presence of </span></span>charnockites<span><span> and layered gabbro-anorthosites and pyroxenites<span>, delineating a stratified intrusive setting. Lodestones exhibit complex mineral assemblage involving magnetite, ilmenite, ulvöspinel, spinel, corundum, hematite, </span></span>goethite, pyrite, </span></span>pyrrhotite<span>, and amphiboles. The bulk rock chemistry of the lodestone is analogues to Fe-Ti magnetite </span></span>iron ore<span> deposits with elevated vanadium and chromium contents. Their resemblance to tholeiitic magma-type suggests their formation in a layered intrusive setting, evolved through multiple fractional crystallization under oxidizing conditions. Thermometric and fugacity calculations using different textural associations estimate the magmatic fractional crystallization stage at elevated temperatures (601–704 °C) and low </span></span><em>f</em>O<sub>2</sub><span> (−18.6 to −15.3), succeeded by the exsolution stage during subsolidus cooling at lower temperatures (379–540 °C) and high </span><em>f</em>O<sub>2</sub><span> (−38.2 to −22.1). The whole sequence of formation and evolution of lodestone encompasses primary magmatic crystallization, subsolidus re-equilibration, metamorphism, and secondary weathering. The study also suggests a genetic linkage of lodestone with the associated mafic-ultramafic units, depicting two possible magmatic processes either through slab melting and fractional crystallization associated with subduction or due to plume magmatism and associated rifting.</span></p></div>\",\"PeriodicalId\":55973,\"journal\":{\"name\":\"Chemie Der Erde-Geochemistry\",\"volume\":\"84 3\",\"pages\":\"Article 126142\"},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2024-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemie Der Erde-Geochemistry\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0009281924000667\",\"RegionNum\":3,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"GEOCHEMISTRY & GEOPHYSICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemie Der Erde-Geochemistry","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0009281924000667","RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"GEOCHEMISTRY & GEOPHYSICS","Score":null,"Total":0}
Origin and thermal evolution of Cr-V-Ti magnetites (lodestones) from Coorg massif, southern India
This study deals with petrology, textural, thermometry, and geochemical characterization of naturally magnetized Cr-V-Ti magnetite deposits within the layered mafic-ultramafic intrusions in Coorg massif of southern India using ore petrography and mineral/whole rock geochemistry. These deposits, also known as ‘lodestones’, occur as rhythmic layers within the lateritized host rock, with the underlying basement distinguished by the presence of charnockites and layered gabbro-anorthosites and pyroxenites, delineating a stratified intrusive setting. Lodestones exhibit complex mineral assemblage involving magnetite, ilmenite, ulvöspinel, spinel, corundum, hematite, goethite, pyrite, pyrrhotite, and amphiboles. The bulk rock chemistry of the lodestone is analogues to Fe-Ti magnetite iron ore deposits with elevated vanadium and chromium contents. Their resemblance to tholeiitic magma-type suggests their formation in a layered intrusive setting, evolved through multiple fractional crystallization under oxidizing conditions. Thermometric and fugacity calculations using different textural associations estimate the magmatic fractional crystallization stage at elevated temperatures (601–704 °C) and low fO2 (−18.6 to −15.3), succeeded by the exsolution stage during subsolidus cooling at lower temperatures (379–540 °C) and high fO2 (−38.2 to −22.1). The whole sequence of formation and evolution of lodestone encompasses primary magmatic crystallization, subsolidus re-equilibration, metamorphism, and secondary weathering. The study also suggests a genetic linkage of lodestone with the associated mafic-ultramafic units, depicting two possible magmatic processes either through slab melting and fractional crystallization associated with subduction or due to plume magmatism and associated rifting.
期刊介绍:
GEOCHEMISTRY was founded as Chemie der Erde 1914 in Jena, and, hence, is one of the oldest journals for geochemistry-related topics.
GEOCHEMISTRY (formerly Chemie der Erde / Geochemistry) publishes original research papers, short communications, reviews of selected topics, and high-class invited review articles addressed at broad geosciences audience. Publications dealing with interdisciplinary questions are particularly welcome. Young scientists are especially encouraged to submit their work. Contributions will be published exclusively in English. The journal, through very personalized consultation and its worldwide distribution, offers entry into the world of international scientific communication, and promotes interdisciplinary discussion on chemical problems in a broad spectrum of geosciences.
The following topics are covered by the expertise of the members of the editorial board (see below):
-cosmochemistry, meteoritics-
igneous, metamorphic, and sedimentary petrology-
volcanology-
low & high temperature geochemistry-
experimental - theoretical - field related studies-
mineralogy - crystallography-
environmental geosciences-
archaeometry