通过咔唑修饰的供体-受体配体以可见光活化 Ru(II) 复合物催化剂，用于二氧化碳还原

IF 1.4 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Chemistry Letters Pub Date : 2024-07-01 DOI:10.1093/chemle/upae127

Akinobu Nakada, Yuya Tomiura, Hajime Suzuki, Osamu Tomita, Ryu Abe

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引用次数: 0

摘要

光催化剂的可见光活化对于有效利用太阳能进行分子转换至关重要。本研究证明，用咔唑修饰联吡啶配体可实现 Ru(II) 羰基复合物催化剂的可见光活化。本研究为在单核复合物中单独设计吸光配体和催化功能开辟了道路。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Visible-Light Activation of a Ru(II) Complex Catalyst via a Carbazole-Modified Donor–Acceptor Ligand for CO2 Reduction

Visible-light activation of photocatalysts is crucial for effectively utilizing solar energy in molecular conversions. This study demonstrates that modifying the bipyridine ligand with carbazole enables visible-light activation of a Ru(II) carbonyl complex catalyst, which is originally developed as an electrocatalyst for CO2 reduction but inactive as a photocatalyst on its own. The present study opens avenues for individually designing light-absorbing ligands and catalytic functions within one mononuclear complex.

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来源期刊

Chemistry Letters 化学-化学综合

CiteScore

3.00

自引率

6.20%

发文量

260

审稿时长

1.2 months

期刊介绍： Chemistry Letters covers the following topics: -Organic Chemistry- Physical Chemistry- Inorganic Chemistry- Analytical Chemistry- Materials Chemistry- Polymer Chemistry- Supramolecular Chemistry- Organometallic Chemistry- Coordination Chemistry- Biomolecular Chemistry- Natural Products and Medicinal Chemistry- Electrochemistry