V. S. Trush, I. M. Pohrelyuk, A. G. Lyk’yanenko, T. M. Kravchyshyn, V. M. Fedirko, V. M. Korendii, I. V. Kovalchuk
{"title":"Zr-1%Nb 合金的气体渗碳动力学","authors":"V. S. Trush, I. M. Pohrelyuk, A. G. Lyk’yanenko, T. M. Kravchyshyn, V. M. Fedirko, V. M. Korendii, I. V. Kovalchuk","doi":"10.1007/s11003-024-00819-1","DOIUrl":null,"url":null,"abstract":"<p>The kinetic characteristics of thin-sheet (approx. 1 mm) Zr–1%Nb alloy samples after treatment in a carbon-containing gas medium (<span>\\({P}_{\\mathrm{Ar}+{\\mathrm{C}}_{3}{\\mathrm{H}}_{8}}\\)</span> = 0.106 Pa) in a wide temperature range of 650–850°C and time 1; 5 and 10 h were investigated. The carburizing of the alloy at temperatures of 650 and 750°C occurs according to a law close to linear (<i>n</i> ≈ 1), and at 850°C according to a law close to parabolic (<i>n</i> ≈ 2). The activation energy of the alloy carburizing in the temperature range of 650–850°C at the propane partial pressure <span>\\({p}_{{\\mathrm{C}}_{3}{\\mathrm{H}}_{8}}\\)</span> = 0.018 Pa was 2.21 kJ/mol. The distribution of microhardness and structure of the near-surface layers of the alloy was shown. The microstructure of the near-surface layers of the alloy after carburizing was determined. The α-Zr and ZrC phase content on the alloy surface after treatment in a carbon-containing gas environment is presented.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":null,"pages":null},"PeriodicalIF":0.7000,"publicationDate":"2024-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Kinetics of Gas Carburizing of Zr–1%Nb Alloy\",\"authors\":\"V. S. Trush, I. M. Pohrelyuk, A. G. Lyk’yanenko, T. M. Kravchyshyn, V. M. Fedirko, V. M. Korendii, I. V. Kovalchuk\",\"doi\":\"10.1007/s11003-024-00819-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The kinetic characteristics of thin-sheet (approx. 1 mm) Zr–1%Nb alloy samples after treatment in a carbon-containing gas medium (<span>\\\\({P}_{\\\\mathrm{Ar}+{\\\\mathrm{C}}_{3}{\\\\mathrm{H}}_{8}}\\\\)</span> = 0.106 Pa) in a wide temperature range of 650–850°C and time 1; 5 and 10 h were investigated. The carburizing of the alloy at temperatures of 650 and 750°C occurs according to a law close to linear (<i>n</i> ≈ 1), and at 850°C according to a law close to parabolic (<i>n</i> ≈ 2). The activation energy of the alloy carburizing in the temperature range of 650–850°C at the propane partial pressure <span>\\\\({p}_{{\\\\mathrm{C}}_{3}{\\\\mathrm{H}}_{8}}\\\\)</span> = 0.018 Pa was 2.21 kJ/mol. The distribution of microhardness and structure of the near-surface layers of the alloy was shown. The microstructure of the near-surface layers of the alloy after carburizing was determined. The α-Zr and ZrC phase content on the alloy surface after treatment in a carbon-containing gas environment is presented.</p>\",\"PeriodicalId\":18230,\"journal\":{\"name\":\"Materials Science\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2024-06-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Science\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1007/s11003-024-00819-1\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Science","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1007/s11003-024-00819-1","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
The kinetic characteristics of thin-sheet (approx. 1 mm) Zr–1%Nb alloy samples after treatment in a carbon-containing gas medium (\({P}_{\mathrm{Ar}+{\mathrm{C}}_{3}{\mathrm{H}}_{8}}\) = 0.106 Pa) in a wide temperature range of 650–850°C and time 1; 5 and 10 h were investigated. The carburizing of the alloy at temperatures of 650 and 750°C occurs according to a law close to linear (n ≈ 1), and at 850°C according to a law close to parabolic (n ≈ 2). The activation energy of the alloy carburizing in the temperature range of 650–850°C at the propane partial pressure \({p}_{{\mathrm{C}}_{3}{\mathrm{H}}_{8}}\) = 0.018 Pa was 2.21 kJ/mol. The distribution of microhardness and structure of the near-surface layers of the alloy was shown. The microstructure of the near-surface layers of the alloy after carburizing was determined. The α-Zr and ZrC phase content on the alloy surface after treatment in a carbon-containing gas environment is presented.
期刊介绍:
Materials Science reports on current research into such problems as cracking, fatigue and fracture, especially in active environments as well as corrosion and anticorrosion protection of structural metallic and polymer materials, and the development of new materials.