{"title":"镍络合物锚定和稳定的 Fe3O4@PEG 核壳纳米圈:用于合成苯并噻唑衍生物的具有超级催化活性的绿色合成纳米催化剂","authors":"Samane Mohammadlou, Nader Noroozi Pesyan","doi":"10.1007/s10563-024-09427-0","DOIUrl":null,"url":null,"abstract":"<div><p>The recent advances in the green-based design and synthesis of core-shell nanostructures have always been an intriguing arena to scientists due to their compelling application in catalytic fields. This work designed and synthesized a new core-shell nanosphere based on Fe<sub>3</sub>O<sub>4</sub> as a novel, heterogeneous, reusable, efficient, and green catalyst to synthesize benzothiazole derivatives under ultrasonic irradiation. To achieve this goal, initially, fabricated Fe<sub>3</sub>O<sub>4</sub> magnetic nanoparticles via the co-operation method were synthesized as a core, followed by coating with polyethylene glycol (PEG-400). Subsequently, Ni@Murexide complex supported on magnetic nanoparticles is successfully synthesized and reported, modified using 3-chloropropyltriethoxysilane (CPTES) and Murexide (MX) ligand in the Fe<sub>3</sub>O<sub>4</sub>@PEG support. The obtained structure of Fe<sub>3</sub>O<sub>4</sub>@PEG/MX/Ni was characterized by different analyses such as FT-IR, SEM, EDS, TEM, ICP-OES, XRD, VSM, and TGA. The results illustrated the effect of ultrasonic irradiation and the high efficacy of Murexide as a ligand in catalyzing the formation of benzothiazole derivatives and confirming the findings from the reaction of different derivatives of aromatic aldehyde with electron-withdrawing/donor groups with 2-amino thiophenol through a one-pot process in 10 min under ultrasonic irradiation which shows the non-sensitivity of the process to electronic effects. Furthermore, Fe<sub>3</sub>O<sub>4</sub>@PEG/MX@Ni showed great use at least six times with no significant loss in catalyst activity.</p></div>","PeriodicalId":509,"journal":{"name":"Catalysis Surveys from Asia","volume":null,"pages":null},"PeriodicalIF":2.1000,"publicationDate":"2024-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Fe3O4@PEG Core-Shell Nanosphere Anchored and Stabilized by Nickel Complex on Murexide: Green Synthesized Nanocatalyst with Super Catalytic Activity for Synthesize of Benzothiazole Derivatives\",\"authors\":\"Samane Mohammadlou, Nader Noroozi Pesyan\",\"doi\":\"10.1007/s10563-024-09427-0\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The recent advances in the green-based design and synthesis of core-shell nanostructures have always been an intriguing arena to scientists due to their compelling application in catalytic fields. This work designed and synthesized a new core-shell nanosphere based on Fe<sub>3</sub>O<sub>4</sub> as a novel, heterogeneous, reusable, efficient, and green catalyst to synthesize benzothiazole derivatives under ultrasonic irradiation. To achieve this goal, initially, fabricated Fe<sub>3</sub>O<sub>4</sub> magnetic nanoparticles via the co-operation method were synthesized as a core, followed by coating with polyethylene glycol (PEG-400). Subsequently, Ni@Murexide complex supported on magnetic nanoparticles is successfully synthesized and reported, modified using 3-chloropropyltriethoxysilane (CPTES) and Murexide (MX) ligand in the Fe<sub>3</sub>O<sub>4</sub>@PEG support. The obtained structure of Fe<sub>3</sub>O<sub>4</sub>@PEG/MX/Ni was characterized by different analyses such as FT-IR, SEM, EDS, TEM, ICP-OES, XRD, VSM, and TGA. The results illustrated the effect of ultrasonic irradiation and the high efficacy of Murexide as a ligand in catalyzing the formation of benzothiazole derivatives and confirming the findings from the reaction of different derivatives of aromatic aldehyde with electron-withdrawing/donor groups with 2-amino thiophenol through a one-pot process in 10 min under ultrasonic irradiation which shows the non-sensitivity of the process to electronic effects. Furthermore, Fe<sub>3</sub>O<sub>4</sub>@PEG/MX@Ni showed great use at least six times with no significant loss in catalyst activity.</p></div>\",\"PeriodicalId\":509,\"journal\":{\"name\":\"Catalysis Surveys from Asia\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2024-06-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Catalysis Surveys from Asia\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10563-024-09427-0\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis Surveys from Asia","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10563-024-09427-0","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Fe3O4@PEG Core-Shell Nanosphere Anchored and Stabilized by Nickel Complex on Murexide: Green Synthesized Nanocatalyst with Super Catalytic Activity for Synthesize of Benzothiazole Derivatives
The recent advances in the green-based design and synthesis of core-shell nanostructures have always been an intriguing arena to scientists due to their compelling application in catalytic fields. This work designed and synthesized a new core-shell nanosphere based on Fe3O4 as a novel, heterogeneous, reusable, efficient, and green catalyst to synthesize benzothiazole derivatives under ultrasonic irradiation. To achieve this goal, initially, fabricated Fe3O4 magnetic nanoparticles via the co-operation method were synthesized as a core, followed by coating with polyethylene glycol (PEG-400). Subsequently, Ni@Murexide complex supported on magnetic nanoparticles is successfully synthesized and reported, modified using 3-chloropropyltriethoxysilane (CPTES) and Murexide (MX) ligand in the Fe3O4@PEG support. The obtained structure of Fe3O4@PEG/MX/Ni was characterized by different analyses such as FT-IR, SEM, EDS, TEM, ICP-OES, XRD, VSM, and TGA. The results illustrated the effect of ultrasonic irradiation and the high efficacy of Murexide as a ligand in catalyzing the formation of benzothiazole derivatives and confirming the findings from the reaction of different derivatives of aromatic aldehyde with electron-withdrawing/donor groups with 2-amino thiophenol through a one-pot process in 10 min under ultrasonic irradiation which shows the non-sensitivity of the process to electronic effects. Furthermore, Fe3O4@PEG/MX@Ni showed great use at least six times with no significant loss in catalyst activity.
期刊介绍:
Early dissemination of important findings from Asia which may lead to new concepts in catalyst design is the main aim of this journal. Rapid, invited, short reviews and perspectives from academia and industry will constitute the major part of Catalysis Surveys from Asia . Surveys of recent progress and activities in catalytic science and technology and related areas in Asia will be covered regularly as well. We would appreciate critical comments from colleagues throughout the world about articles in Catalysis Surveys from Asia . If requested and thought appropriate, the comments will be included in the journal. We will be very happy if this journal stimulates global communication between scientists and engineers in the world of catalysis.