{"title":"与 3-苯基丙基丙二酸的铜（II）配合物的合成、结构和电化学性质","authors":"X. Ma, B. Wang, E. Gao","doi":"10.1134/S0022476624050135","DOIUrl":null,"url":null,"abstract":"<p>A 0D Cu-based complex (<b>1</b>) (Cu(L)<sub>2</sub>(EDA)<sub>2</sub>]<sub><i>n</i></sub>, L = 3-phenylpropylmalonic acid, EDA = ethylenediamine) is synthesized by the solvent-thermal synthesis using 3-phenylpropylmalonic acid as the ligand. It is characterized and analyzed by powder X-ray diffraction, IR and UV diffuse reflectance spectroscopy, and other techniques. Complex<b> 1</b> crystallizes in the triclinic crystal system with space group <span>\\(P\\bar{1}\\)</span>, and each Cu<sup>2+</sup> is coordinated with two ligands and a water molecule, respectively. The cyclic voltammetry curve of the electrode modified by <b>1</b> (1+CPE) is tested in the PBS buffer solution (pH = 6.5). The found pair of reversible redox peaks belonging to Cu(II)/Cu(I) prove that <b>1</b> can be used in electrochemical applications.</p>","PeriodicalId":668,"journal":{"name":"Journal of Structural Chemistry","volume":"65 5","pages":"1002 - 1009"},"PeriodicalIF":1.2000,"publicationDate":"2024-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis, Structrure, and Eletrochemical Properties of a Copper(II) Complex with 3-Phenylpropylmalonic Acid\",\"authors\":\"X. Ma, B. Wang, E. Gao\",\"doi\":\"10.1134/S0022476624050135\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>A 0D Cu-based complex (<b>1</b>) (Cu(L)<sub>2</sub>(EDA)<sub>2</sub>]<sub><i>n</i></sub>, L = 3-phenylpropylmalonic acid, EDA = ethylenediamine) is synthesized by the solvent-thermal synthesis using 3-phenylpropylmalonic acid as the ligand. It is characterized and analyzed by powder X-ray diffraction, IR and UV diffuse reflectance spectroscopy, and other techniques. Complex<b> 1</b> crystallizes in the triclinic crystal system with space group <span>\\\\(P\\\\bar{1}\\\\)</span>, and each Cu<sup>2+</sup> is coordinated with two ligands and a water molecule, respectively. The cyclic voltammetry curve of the electrode modified by <b>1</b> (1+CPE) is tested in the PBS buffer solution (pH = 6.5). The found pair of reversible redox peaks belonging to Cu(II)/Cu(I) prove that <b>1</b> can be used in electrochemical applications.</p>\",\"PeriodicalId\":668,\"journal\":{\"name\":\"Journal of Structural Chemistry\",\"volume\":\"65 5\",\"pages\":\"1002 - 1009\"},\"PeriodicalIF\":1.2000,\"publicationDate\":\"2024-06-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Structural Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0022476624050135\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Structural Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0022476624050135","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Synthesis, Structrure, and Eletrochemical Properties of a Copper(II) Complex with 3-Phenylpropylmalonic Acid
A 0D Cu-based complex (1) (Cu(L)2(EDA)2]n, L = 3-phenylpropylmalonic acid, EDA = ethylenediamine) is synthesized by the solvent-thermal synthesis using 3-phenylpropylmalonic acid as the ligand. It is characterized and analyzed by powder X-ray diffraction, IR and UV diffuse reflectance spectroscopy, and other techniques. Complex 1 crystallizes in the triclinic crystal system with space group \(P\bar{1}\), and each Cu2+ is coordinated with two ligands and a water molecule, respectively. The cyclic voltammetry curve of the electrode modified by 1 (1+CPE) is tested in the PBS buffer solution (pH = 6.5). The found pair of reversible redox peaks belonging to Cu(II)/Cu(I) prove that 1 can be used in electrochemical applications.
期刊介绍：
Journal is an interdisciplinary publication covering all aspects of structural chemistry, including the theory of molecular structure and chemical bond; the use of physical methods to study the electronic and spatial structure of chemical species; structural features of liquids, solutions, surfaces, supramolecular systems, nano- and solid materials; and the crystal structure of solids.
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