利用双功能电化学反应器连续合成己硝基苯乙烯

IF 3.4 3区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Reaction Chemistry & Engineering Pub Date : 2024-06-19 DOI:10.1039/D4RE00110A

Yuqiu Wang, Guangyuan Zhang, Shuaijie Jiang, Ming Lu and Pengcheng Wang

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引用次数: 0

摘要

电化学反应器的采用有效缓解了工业生产过程中对环境不利的挑战。本文介绍了一种使用双功能电化学反应器合成己硝基苯乙烯的环保型新方法，该方法可有效混合原料并同时将 C-C 键转化为 CC 键。产量的显著提高证实了这一方法的有效性，在 8 毫安电流下持续 30 分钟后，产量从 36% 提高到 58.5%。此外，纯度也从 86% 提高到 98.2%，同时己硝基苯乙烯的分解温度也显著提高。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Continuous synthesis of hexanitrostilbene using a difunctional electrochemical reactor†

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Continuous synthesis of hexanitrostilbene using a difunctional electrochemical reactor†

The adoption of electrochemical reactors has effectively mitigated the environmentally detrimental challenges in industrial manufacturing processes. A novel method for the eco-friendly synthesis of hexanitrostilbene using a difunctional electrochemical reactor is introduced, facilitating effective blending of feedstock and transformation of C–C bonds into CC bonds simultaneously. The effectiveness has been confirmed by significant improvements in yield, increasing from 36% to 58.5% when exposed to 8 mA current for 30 min. Moreover, the purity rose from 86% to 98.2%, accompanied by a notable elevation in the decomposition temperature of hexanitrostilbene.

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来源期刊

Reaction Chemistry & Engineering Chemistry-Chemistry (miscellaneous)

CiteScore

6.60

自引率

7.70%

发文量

227

期刊介绍： Reaction Chemistry & Engineering is a new journal reporting cutting edge research into all aspects of making molecules for the benefit of fundamental research, applied processes and wider society. From fundamental, molecular-level chemistry to large scale chemical production, Reaction Chemistry & Engineering brings together communities of chemists and chemical engineers working to ensure the crucial role of reaction chemistry in today’s world.