通过钯催化 C-H 键官能化合成多核芳香烃

IF 1.7 3区化学 Q3 CHEMISTRY, ORGANIC

Current Organic Chemistry Pub Date : 2024-06-24 DOI:10.2174/0113852728283702240605113835

Mitali Dewan, Sachinath Bera, Shubhankar Samanta, Debasish Kundu, Rathin Jana

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引用次数: 0

摘要

:如今，钯催化 C-H 键活化是一种有用的有机化合物合成转化方法，它具有步骤经济、使用非预官能化底物和减少化学废物等优点。在各种合成策略中，钯催化分子内和分子间 C-H 键活化最近在合成装饰性 π 共轭多环芳烃方面引起了广泛关注。在本综述中，我们重点介绍了利用 Pd 催化 C-H 键活化合成各种多核芳烃 (PAH) 的最新进展和以往的策略。我们还讨论了分子内和分子间 C-H 键活化反应的机理细节。

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Synthesis of Polynuclear Aromatic Hydrocarbons by Palladium-catalyzed C-H Bond Functionalization

: Nowadays palladium-catalyzed C–H bond activation is a useful approach for the synthetic transformation of organic compounds due to step economy, the use of non-prefunctionalized substrates and reduced chemical wastes. Among the various synthetic strategies, palladium catalyzed intra and inter-molecular C–H bond activation has recently drawn a lot of interest to synthesize the decorated π-conjugated polycyclic aromatic hydrocarbon. In this review, we have focused on recent progress along with previous strategies to synthesize various polynuclear aromatic hydrocarbons (PAHs) by the use of Pd-catalyzed C–H bond activation. We have also discussed the mechanistic details of the reaction intra and inter-molecular C–H bond activation.

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来源期刊

Current Organic Chemistry 化学-有机化学

CiteScore

3.70

自引率

7.70%

发文量

审稿时长

1 months

期刊介绍： Current Organic Chemistry aims to provide in-depth/mini reviews on the current progress in various fields related to organic chemistry including bioorganic chemistry, organo-metallic chemistry, asymmetric synthesis, heterocyclic chemistry, natural product chemistry, catalytic and green chemistry, suitable aspects of medicinal chemistry and polymer chemistry, as well as analytical methods in organic chemistry. The frontier reviews provide the current state of knowledge in these fields and are written by chosen experts who are internationally known for their eminent research contributions. The Journal also accepts high quality research papers focusing on hot topics, highlights and letters besides thematic issues in these fields. Current Organic Chemistry should prove to be of great interest to organic chemists in academia and industry, who wish to keep abreast with recent developments in key fields of organic chemistry.